High-valent metals in advanced oxidation processes: A critical review of their identification methods, formation mechanisms, and reactivity performance
B Yang, H Liu, J Zhang - Chemical Engineering Journal, 2023 - Elsevier
The role of high-valent metals as dominant reactive oxidants in advanced oxidation
processes (AOPs) has not been systematically reviewed. The aim of this study was to …
processes (AOPs) has not been systematically reviewed. The aim of this study was to …
Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration
W Huang, X Ma, O Sato, D Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …
which many metal atoms and organic ligands are integrated to synergize their properties. As …
High-valent cobalt-oxo species triggers hydroxyl radical for collaborative environmental decontamination
The overlooked role of high-valent cobalt-oxo species (Co (IV)) in the Co
(II)/peroxymonosulfate (PMS) process was uncovered recently using methyl phenyl sulfoxide …
(II)/peroxymonosulfate (PMS) process was uncovered recently using methyl phenyl sulfoxide …
Control of electronic polarization via charge ordering and electron transfer: electronic ferroelectrics and electronic pyroelectrics
SQ Su, SQ Wu, S Kanegawa, K Yamamoto… - Chemical Science, 2023 - pubs.rsc.org
Ferroelectric, pyroelectric, and piezoelectric compounds whose electric polarization
properties can be controlled by external stimuli such as electric field, temperature, and …
properties can be controlled by external stimuli such as electric field, temperature, and …
Metal‐to‐Ligand Charge Transfer Induced Valence Tautomeric Forms of Non‐Innocent 2, 2′‐Azobis (benzothiazole) in Ruthenium Frameworks
The impact of metal‐to‐ligand charge transfer towards the redox noninnocence of 2, 2′‐
azobis (benzothiazole)(abbt) has been highlighted on coordination to {RuII (acac) 2}(acac …
azobis (benzothiazole)(abbt) has been highlighted on coordination to {RuII (acac) 2}(acac …
Controlling Spin Crossover in a Family of Dinuclear Fe (III) Complexes via the Bis (catecholate) Bridging Ligand
JT Janetzki, MG Chegerev, GK Gransbury… - Inorganic …, 2023 - ACS Publications
Spin crossover (SCO) complexes can reversibly switch between low spin (LS) and high spin
(HS) states, affording possible applications in sensing, displays, and molecular electronics …
(HS) states, affording possible applications in sensing, displays, and molecular electronics …
Assembling Smallest Prussian Blue Analogs Using Chiral Hydrogen Bond-Donating Unit toward Complete Phase Transition
Exploring methods for assembling functional materials at the molecular level may yield
functional expressions derived from the assembly method. This study developed novel …
functional expressions derived from the assembly method. This study developed novel …
Modulation of Charge Distribution in Cobalt-α-Diimine Complexes toward Valence Tautomerism
MA Hay, JT Janetzki, VJ Kumar, RW Gable… - Inorganic …, 2022 - ACS Publications
Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for developing
a range of molecular materials for sensing, memory, and optoelectronic applications …
a range of molecular materials for sensing, memory, and optoelectronic applications …
Valence tautomerism in a cobalt–dioxolene complex containing an imidazolic ancillary ligand
AMV Guedes, LS de Abreu, IAV Maldonado… - RSC …, 2023 - pubs.rsc.org
This work reports the synthesis, structural, spectroscopic and magnetic investigation of two
complexes,[Co (bmimapy)(3, 5-DTBCat)] PF6· H2O (1) and [Co (bmimapy)(TCCat)] PF6 …
complexes,[Co (bmimapy)(3, 5-DTBCat)] PF6· H2O (1) and [Co (bmimapy)(TCCat)] PF6 …
A convenient DFT-based strategy for predicting transition temperatures of valence tautomeric molecular switches
The ability to identify promising candidate switchable molecules computationally, prior to
synthesis, represents a considerable advance in the development of switchable molecular …
synthesis, represents a considerable advance in the development of switchable molecular …