High-valent metals in advanced oxidation processes: A critical review of their identification methods, formation mechanisms, and reactivity performance

B Yang, H Liu, J Zhang - Chemical Engineering Journal, 2023 - Elsevier
The role of high-valent metals as dominant reactive oxidants in advanced oxidation
processes (AOPs) has not been systematically reviewed. The aim of this study was to …

Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration

W Huang, X Ma, O Sato, D Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …

High-valent cobalt-oxo species triggers hydroxyl radical for collaborative environmental decontamination

Y Zong, H Zhang, X Zhang, W Liu, L Xu… - Applied Catalysis B …, 2022 - Elsevier
The overlooked role of high-valent cobalt-oxo species (Co (IV)) in the Co
(II)/peroxymonosulfate (PMS) process was uncovered recently using methyl phenyl sulfoxide …

Control of electronic polarization via charge ordering and electron transfer: electronic ferroelectrics and electronic pyroelectrics

SQ Su, SQ Wu, S Kanegawa, K Yamamoto… - Chemical Science, 2023 - pubs.rsc.org
Ferroelectric, pyroelectric, and piezoelectric compounds whose electric polarization
properties can be controlled by external stimuli such as electric field, temperature, and …

Metal‐to‐Ligand Charge Transfer Induced Valence Tautomeric Forms of Non‐Innocent 2, 2′‐Azobis (benzothiazole) in Ruthenium Frameworks

A Singh, S Panda, S Dey, GK Lahiri - Angewandte Chemie, 2021 - Wiley Online Library
The impact of metal‐to‐ligand charge transfer towards the redox noninnocence of 2, 2′‐
azobis (benzothiazole)(abbt) has been highlighted on coordination to {RuII (acac) 2}(acac …

Controlling Spin Crossover in a Family of Dinuclear Fe (III) Complexes via the Bis (catecholate) Bridging Ligand

JT Janetzki, MG Chegerev, GK Gransbury… - Inorganic …, 2023 - ACS Publications
Spin crossover (SCO) complexes can reversibly switch between low spin (LS) and high spin
(HS) states, affording possible applications in sensing, displays, and molecular electronics …

Assembling Smallest Prussian Blue Analogs Using Chiral Hydrogen Bond-Donating Unit toward Complete Phase Transition

R Fukushima, Y Sekine, Z Zhang… - Journal of the American …, 2024 - ACS Publications
Exploring methods for assembling functional materials at the molecular level may yield
functional expressions derived from the assembly method. This study developed novel …

Modulation of Charge Distribution in Cobalt-α-Diimine Complexes toward Valence Tautomerism

MA Hay, JT Janetzki, VJ Kumar, RW Gable… - Inorganic …, 2022 - ACS Publications
Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for developing
a range of molecular materials for sensing, memory, and optoelectronic applications …

Valence tautomerism in a cobalt–dioxolene complex containing an imidazolic ancillary ligand

AMV Guedes, LS de Abreu, IAV Maldonado… - RSC …, 2023 - pubs.rsc.org
This work reports the synthesis, structural, spectroscopic and magnetic investigation of two
complexes,[Co (bmimapy)(3, 5-DTBCat)] PF6· H2O (1) and [Co (bmimapy)(TCCat)] PF6 …

A convenient DFT-based strategy for predicting transition temperatures of valence tautomeric molecular switches

JT Janetzki, FZM Zahir, RW Gable, W Phonsri… - Inorganic …, 2021 - ACS Publications
The ability to identify promising candidate switchable molecules computationally, prior to
synthesis, represents a considerable advance in the development of switchable molecular …