Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Chiral amines are key structural motifs present in a wide variety of natural products, drugs,
and other biologically active compounds. During the past decade, significant advances have …

β2-Amino carbonyls, an α-substituted β-amino scaffold, hold a prominent place in the
development of new pharmaceuticals and peptidomimetics. Herein, we report a highly …

A N-heterocyclic carbene-catalyzed (NHC) three-component reaction involving N-
aminopyridinium salts, alkenes, and aldehydes for the synthesis of β-amino ketones is …

An amidoarylcarbonylation reaction of aromatic aldehydes and olefins with Katritzky
pyridinium salts by N-heterocyclic carbene (NHC)-catalyzed radical relay to construct C–C …

A highly site-selective acyloxylation of stable enamines with PhI (OAc) 2 under metal-free
conditions to afford (E)-vinyl acetate derivatives in good to excellent yields is described …

A highly efficient iridium-catalyzed asymmetric hydrogenation of tetrasubstituted cyclic
enones has been developed for the enantioselective synthesis of chiral cycloalkanols with …

Catalyzed by a rhodium complex of P-stereogenic diphosphine ligand (R)-2-tert-
butylmethylphosphino-3-(di-tert-butylphosphino) quinoxaline ((R)-3H-QuinoxP*), five …

A feasible and umpolung strategy for the synthesis of structurally diverse β‐amino ketones
has been achieved through TEMPO mediated C− N coupling of cyclopropanols with …

A visible light photoredox-catalyzed N-centered radical addition/semipinacol rearrangement
cascade of cycloalkanol-substituted 1H-indenes or styrenes with N-arylsulfonyl protected 1 …