Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical
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The selective transformation of ubiquitous but inert C–H bonds to other functional groups
has far-reaching practical implications, ranging from more efficient strategies for fine …

Hydrocarbons, especially saturated hydrocarbons (alkanes), are the main constituents of oil
and natural gas, the feedstocks for chemical industry. Therefore, it is obvious that …

Synthetic methods chemistry has undergoneintense development during the past 50 years.
As a result, nearly every class of organic compound can now be considered as a source of …

At one time the synthetic chemist's last resort, reactions catalysed by transition metals are
now the preferred method for synthesizing many types of organic molecule. A recent …

Hydrocarbons and their transformations play major roles in chemistry as raw materials and
sources of energy. Diminishing petroleum supplies, regulatory problems, and environmental …

The formation of a single product from terminal functionalization of linear alkanes from a
transition metal–catalyzed reaction is reported. The rhodium complex Cp* Rh (η4 …

A new class of coordinatively unsaturated, monomeric organoscandiumcompounds, Cp*
2Sc-R (Cp*=(rj5-C5Me5); R= halide, hydride, alkyl, alkenyl, alkynyl, aryl), has been …

Hydrocarbons are readily available from inexpensive petrochemical and natural gas
feedstock and have been utilized as raw materials for the production of materials and energy …

This paper describes mechanistic studies on the functionalization of arenes with the diboron
reagent B2pin2 (bis-pinacolato diborane (4)) catalyzed by the combination of 4, 4 '-di-tert …