There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Dinuclear complexes of early-transition metals of group 5 (Nb and Ta), 6 (Cr, Mo, and W),
and 7 (Re) tend to form multiple bonds between two metal centers, ie., double, triple …

The year 2017 marks the 10th anniversary of the passing of Prof. F. Albert Cotton, who
described the first metal− metal multiple bonds in 1964. 1 Cotton's contributions to our …

Copper (II) complexes of quinoline-based ligands were synthesized, and their catalytic
properties in atom transfer radical addition (ATRA) reactions of alkyl halides to alkenes were …

Multimetallic catalysts exhibit great potential in the activation and catalytic transformation of
small molecules. The polarized metal–metal bonds have been gradually recognized to …

The optical and electrochemical properties of quadruply bonded dimolybdenum
paddlewheel complexes (Mo2PWCs) make them ideal candidates for incorporation into …

Selective decarbonylation of p-nitrophenol esters of fatty acids to the corresponding linear α-
olefins (LAOs) was achieved using palladium catalysis. After extensive ligand screening, a …

A highly efficient Cu-catalyzed 1, 4-difunctionalization of isoquinolinium salts was developed
with ether and X–(X= Br, Cl) as the halogen source under mild conditions. This …

Herein we report the employment of the quintuply bonded dichromium amidinates [Cr {κ2‐
HC (N‐2, 6‐iPr2C6H3)(N‐2, 6‐R2C6H3)}] 2 (R= iPr (1), Me (7)) as catalysts to mediate the …