Small molecule activation with bimetallic systems: a landscape of cooperative reactivity
M Navarro, JJ Moreno, M Pérez-Jiménez… - Chemical …, 2022 - pubs.rsc.org
There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …
emerged due to their potential for bond activation and catalysis, a feature widely exploited …
Cooperative effects in multimetallic complexes applied in catalysis
The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …
catalyze organic transformations to yield the desired products in more efficient ways owing …
Multiply-bonded dinuclear complexes of early-transition metals as minimum entities of metal cluster catalysts
S Rej, H Tsurugi, K Mashima - Coordination Chemistry Reviews, 2018 - Elsevier
Dinuclear complexes of early-transition metals of group 5 (Nb and Ta), 6 (Cr, Mo, and W),
and 7 (Re) tend to form multiple bonds between two metal centers, ie., double, triple …
and 7 (Re) tend to form multiple bonds between two metal centers, ie., double, triple …
Metal–metal bonds: from fundamentals to applications
JF Berry, CC Lu - Inorganic chemistry, 2017 - ACS Publications
The year 2017 marks the 10th anniversary of the passing of Prof. F. Albert Cotton, who
described the first metal− metal multiple bonds in 1964. 1 Cotton's contributions to our …
described the first metal− metal multiple bonds in 1964. 1 Cotton's contributions to our …
Copper (II) complexes of quinoline-based ligands for efficient photoredox catalysis of atom transfer radical addition (ATRA) reaction
P Chaibuth, N Chuaytanee, J Hojitsiriyanont… - New Journal of …, 2022 - pubs.rsc.org
Copper (II) complexes of quinoline-based ligands were synthesized, and their catalytic
properties in atom transfer radical addition (ATRA) reactions of alkyl halides to alkenes were …
properties in atom transfer radical addition (ATRA) reactions of alkyl halides to alkenes were …
Gas-phase reactions driven by polarized metal–metal bonding in atomic clusters
XN Li, SG He - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Multimetallic catalysts exhibit great potential in the activation and catalytic transformation of
small molecules. The polarized metal–metal bonds have been gradually recognized to …
small molecules. The polarized metal–metal bonds have been gradually recognized to …
Enhancing the air stability of dimolybdenum paddlewheel complexes: Redox tuning through fluorine substituents
IAZ Squire, CA Goult, BC Thompson… - Inorganic …, 2022 - ACS Publications
The optical and electrochemical properties of quadruply bonded dimolybdenum
paddlewheel complexes (Mo2PWCs) make them ideal candidates for incorporation into …
paddlewheel complexes (Mo2PWCs) make them ideal candidates for incorporation into …
Selective decarbonylation of fatty acid esters to linear α-olefins
Selective decarbonylation of p-nitrophenol esters of fatty acids to the corresponding linear α-
olefins (LAOs) was achieved using palladium catalysis. After extensive ligand screening, a …
olefins (LAOs) was achieved using palladium catalysis. After extensive ligand screening, a …
Construction of C(sp2)–X (X = Br, Cl) Bonds through a Copper-Catalyzed Atom-Transfer Radical Process: Application for the 1,4-Difunctionalization of Isoquinolinium …
Q Sun, YY Zhang, J Sun, Y Han, X Jia, CG Yan - Organic letters, 2018 - ACS Publications
A highly efficient Cu-catalyzed 1, 4-difunctionalization of isoquinolinium salts was developed
with ether and X–(X= Br, Cl) as the halogen source under mild conditions. This …
with ether and X–(X= Br, Cl) as the halogen source under mild conditions. This …
Reversible cleavage/formation of the chromium–chromium quintuple bond in the highly regioselective alkyne cyclotrimerization
YS Huang, GT Huang, YL Liu, JSK Yu… - Angewandte …, 2017 - Wiley Online Library
Herein we report the employment of the quintuply bonded dichromium amidinates [Cr {κ2‐
HC (N‐2, 6‐iPr2C6H3)(N‐2, 6‐R2C6H3)}] 2 (R= iPr (1), Me (7)) as catalysts to mediate the …
HC (N‐2, 6‐iPr2C6H3)(N‐2, 6‐R2C6H3)}] 2 (R= iPr (1), Me (7)) as catalysts to mediate the …