Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Nitroxide‐mediated polymerization of methacrylic esters: insights and solutions to a long‐standing problem

E Guégain, Y Guillaneuf… - Macromolecular rapid …, 2015 - Wiley Online Library
Nitroxide‐mediated polymerization (NMP) is one of the most powerful reversible
deactivation radical polymerization techniques and has incredibly gained in maturity and …

Radical polymerization in industry

P Nesvadba - Encyclopedia of radicals in chemistry, biology …, 2012 - Wiley Online Library
The position of radical polymerization (RP) in the context of polymer industry is highlighted.
The mechanistic steps of RP are discussed from an industrial point of view. An overview of …

Double modular modification of thiolactone-containing polymers: towards polythiols and derived structures

P Espeel, F Goethals, MM Stamenović, L Petton… - Polymer …, 2012 - pubs.rsc.org
A conceptual proof for the double modification (aminolysis and subsequent thiol-click
modification) of thiolactone units, incorporated in linear polymer scaffolds, was elaborated …

First peptide/protein PEGylation with functional polymers designed by nitroxide-mediated polymerization

M Chenal, C Boursier, Y Guillaneuf, M Taverna… - Polymer …, 2011 - pubs.rsc.org
Well-defined fluorescent, α-functional polymethacrylates with PEG side chains were readily
designed by nitroxide-mediated polymerization (NMP) from N-hydroxysuccinimidyl (NHS) …

Metal free reversible-deactivation radical polymerizations: advances, challenges, and opportunities

J Kreutzer, Y Yagci - Polymers, 2017 - mdpi.com
A considerable amount of the worldwide industrial production of synthetic polymers is
currently based on radical polymerization methods. The steadily increasing demand on high …

Fluorescent, Thermoresponsive Oligo(ethylene glycol) Methacrylate/9-(4-Vinylbenzyl)-9H-carbazole Copolymers Designed with Multiple LCSTs via Nitroxide …

BH Lessard, EJY Ling, M Marić - Macromolecules, 2012 - ACS Publications
9-(4-Vinylbenzyl)-9 H-carbazole (VBK) was used as the “controlling” comonomer for
nitroxide mediated polymerization with 10 mol% SG1 free nitroxide relative to BlocBuilder …

A ring to rule them all: a cyclic ketene acetal comonomer controls the nitroxide-mediated polymerization of methacrylates and confers tunable degradability

V Delplace, E Guégain, S Harrisson… - Chemical …, 2015 - pubs.rsc.org
2-Methylene-4-phenyl-1, 3-dioxolane (MPDL) was successfully used as a controlling
comonomer in NMP with oligo (ethylene glycol) methyl ether methacrylate (MeOEGMA) to …

Nitroxide-mediated miniemulsion polymerization of bio-based methacrylates

S Tajbakhsh, F Hajiali, M Marić - Industrial & Engineering …, 2020 - ACS Publications
Nitroxide-mediated homopolymerization and statistical copolymerization of commercially
available methacrylates derived from sustainable feedstocks (isobornyl methacrylate …

History of nitroxide mediated polymerization in Canada

M Marić - The Canadian Journal of Chemical Engineering, 2021 - Wiley Online Library
Nitroxide mediated polymerization (NMP), sometimes known as stable free radical
polymerization (SFRP), is considered one of the main types of reversible deactivation radical …