Taking advantage of disorder: amorphous calcium carbonate and its roles in biomineralization
Amorphous calcium carbonate (ACC) in its pure form is highly unstable, yet some organisms
produce stable ACC, and cases are known in which ACC functions as a transient precursor …
produce stable ACC, and cases are known in which ACC functions as a transient precursor …
Controlling mineral morphologies and structures in biological and synthetic systems
FC Meldrum, H Cölfen - Chemical reviews, 2008 - ACS Publications
The unique and frequently beautiful morphologies that characterize many biominerals have
long been a source of fascination. While research began by looking first at individual …
long been a source of fascination. While research began by looking first at individual …
Microscopic Evidence for Liquid-Liquid Separation in Supersaturated CaCO3 Solutions
Recent experimental observations of the onset of calcium carbonate (CaCO3) mineralization
suggest the emergence of a population of clusters that are stable rather than unstable as …
suggest the emergence of a population of clusters that are stable rather than unstable as …
Organic–inorganic covalent–ionic molecules for elastic ceramic plastic
Although organic–inorganic hybrid materials have played indispensable roles as
mechanical,,–, optical,, electronic, and biomedical materials,–, isolated organic–inorganic …
mechanical,,–, optical,, electronic, and biomedical materials,–, isolated organic–inorganic …
Biomimetic model systems for investigating the amorphous precursor pathway and its role in biomineralization
LB Gower - Chemical reviews, 2008 - ACS Publications
Biologically formed hard tissues, referred to as biominerals, have intrigued the materials
engineering community for years because of the high degree of crystallographic control that …
engineering community for years because of the high degree of crystallographic control that …
[HTML][HTML] Dehydration and crystallization of amorphous calcium carbonate in solution and in air
The mechanisms by which amorphous intermediates transform into crystalline materials are
poorly understood. Currently, attracting enormous interest is the crystallization of amorphous …
poorly understood. Currently, attracting enormous interest is the crystallization of amorphous …
Pressure-driven fusion of amorphous particles into integrated monoliths
Biological organisms can use amorphous precursors to produce inorganic skeletons with
continuous structures through complete particle fusion. Synthesizing monoliths is much …
continuous structures through complete particle fusion. Synthesizing monoliths is much …
Matrix polyelectrolyte microcapsules: new system for macromolecule encapsulation
DV Volodkin, AI Petrov, M Prevot, GB Sukhorukov - Langmuir, 2004 - ACS Publications
A new approach to fabricate polyelectrolyte microcapsules is based on exploiting porous
inorganic microparticles of calcium carbonate. Porous CaCO3 microparticles (4.5− 5.0 …
inorganic microparticles of calcium carbonate. Porous CaCO3 microparticles (4.5− 5.0 …
Kinetic analysis of solid-state reactions: the universality of master plots for analyzing isothermal and nonisothermal experiments
FJ Gotor, JM Criado, J Malek… - The journal of physical …, 2000 - ACS Publications
Master plot methods based on the integral and/or the differential forms of the kinetic
equation describing solid-state reactions have been redefined by using the concept of the …
equation describing solid-state reactions have been redefined by using the concept of the …
Transformation and crystallization energetics of synthetic and biogenic amorphous calcium carbonate
Amorphous calcium carbonate (ACC) is a metastable phase often observed during low
temperature inorganic synthesis and biomineralization. ACC transforms with aging or …
temperature inorganic synthesis and biomineralization. ACC transforms with aging or …