Taking advantage of disorder: amorphous calcium carbonate and its roles in biomineralization

L Addadi, S Raz, S Weiner - Advanced Materials, 2003 - Wiley Online Library
Amorphous calcium carbonate (ACC) in its pure form is highly unstable, yet some organisms
produce stable ACC, and cases are known in which ACC functions as a transient precursor …

Controlling mineral morphologies and structures in biological and synthetic systems

FC Meldrum, H Cölfen - Chemical reviews, 2008 - ACS Publications
The unique and frequently beautiful morphologies that characterize many biominerals have
long been a source of fascination. While research began by looking first at individual …

Microscopic Evidence for Liquid-Liquid Separation in Supersaturated CaCO3 Solutions

AF Wallace, LO Hedges, A Fernandez-Martinez… - Science, 2013 - science.org
Recent experimental observations of the onset of calcium carbonate (CaCO3) mineralization
suggest the emergence of a population of clusters that are stable rather than unstable as …

Organic–inorganic covalent–ionic molecules for elastic ceramic plastic

W Fang, Z Mu, Y He, K Kong, K Jiang, R Tang, Z Liu - Nature, 2023 - nature.com
Although organic–inorganic hybrid materials have played indispensable roles as
mechanical,,–, optical,, electronic, and biomedical materials,–, isolated organic–inorganic …

Biomimetic model systems for investigating the amorphous precursor pathway and its role in biomineralization

LB Gower - Chemical reviews, 2008 - ACS Publications
Biologically formed hard tissues, referred to as biominerals, have intrigued the materials
engineering community for years because of the high degree of crystallographic control that …

[HTML][HTML] Dehydration and crystallization of amorphous calcium carbonate in solution and in air

J Ihli, WC Wong, EH Noel, YY Kim, AN Kulak… - Nature …, 2014 - nature.com
The mechanisms by which amorphous intermediates transform into crystalline materials are
poorly understood. Currently, attracting enormous interest is the crystallization of amorphous …

Pressure-driven fusion of amorphous particles into integrated monoliths

Z Mu, K Kong, K Jiang, H Dong, X Xu, Z Liu, R Tang - Science, 2021 - science.org
Biological organisms can use amorphous precursors to produce inorganic skeletons with
continuous structures through complete particle fusion. Synthesizing monoliths is much …

Matrix polyelectrolyte microcapsules: new system for macromolecule encapsulation

DV Volodkin, AI Petrov, M Prevot, GB Sukhorukov - Langmuir, 2004 - ACS Publications
A new approach to fabricate polyelectrolyte microcapsules is based on exploiting porous
inorganic microparticles of calcium carbonate. Porous CaCO3 microparticles (4.5− 5.0 …

Kinetic analysis of solid-state reactions: the universality of master plots for analyzing isothermal and nonisothermal experiments

FJ Gotor, JM Criado, J Malek… - The journal of physical …, 2000 - ACS Publications
Master plot methods based on the integral and/or the differential forms of the kinetic
equation describing solid-state reactions have been redefined by using the concept of the …

Transformation and crystallization energetics of synthetic and biogenic amorphous calcium carbonate

AV Radha, TZ Forbes, CE Killian… - Proceedings of the …, 2010 - National Acad Sciences
Amorphous calcium carbonate (ACC) is a metastable phase often observed during low
temperature inorganic synthesis and biomineralization. ACC transforms with aging or …