Catalytic three-component dicarbofunctionalization reactions involving radical capture by nickel
S Zhu, X Zhao, H Li, L Chu - Chemical Society Reviews, 2021 - pubs.rsc.org
The catalytic dicarbofunctionalization of unsaturated π bonds represents a powerful platform
for the rapid construction of complex motifs. Despite remarkable progress, novel and efficient …
for the rapid construction of complex motifs. Despite remarkable progress, novel and efficient …
Anti-Markovnikov intermolecular hydroamination of alkenes and alkynes: a mechanistic view
Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …
a great synthetic potential. Important advances have been made in the last decades …
Nitrene transfer and carbene transfer in gold catalysis
LW Ye, XQ Zhu, RL Sahani, Y Xu, PC Qian… - Chemical …, 2020 - ACS Publications
Catalytic transformations involving metal carbenes are considered one of the most important
aspects of homogeneous transition metal catalysis. Recently, gold-catalyzed generation of …
aspects of homogeneous transition metal catalysis. Recently, gold-catalyzed generation of …
Divergent gold catalysis: unlocking molecular diversity through catalyst control
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …
emerged as a promising technique as it allows chartering of structurally distinct products …
Optimization of catalysts and conditions in gold (I) catalysis—counterion and additive effects
Z Lu, T Li, SR Mudshinge, B Xu… - Chemical …, 2021 - ACS Publications
Gold catalysis has proven to be an important breakthrough for organic synthesis. The
tunable nature of gold catalysts, the unique properties of gold, and the mild reaction …
tunable nature of gold catalysts, the unique properties of gold, and the mild reaction …
Expanding the synthetic toolbox through metal–enzyme cascade reactions
S González-Granda, J Albarrán-Velo… - Chemical …, 2023 - ACS Publications
The combination of metal-, photo-, enzyme-, and/or organocatalysis provides multiple
synthetic solutions, especially when the creation of chiral centers is involved. Historically …
synthetic solutions, especially when the creation of chiral centers is involved. Historically …
The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …
Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis
L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …
advances. This includes the synthesis of the first examples of several compound classes that …
Photoredox catalysis in organic chemistry
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a
powerful strategy for the activation of small molecules. In a general sense, these approaches …
powerful strategy for the activation of small molecules. In a general sense, these approaches …
Gold-catalyzed synthesis of small rings
M Mato, A Franchino, C Garcı́a-Morales… - Chemical …, 2020 - ACS Publications
Three-and four-membered rings, widespread motifs in nature and medicinal chemistry, have
fascinated chemists ever since their discovery. However, due to energetic considerations …
fascinated chemists ever since their discovery. However, due to energetic considerations …