Catalytic three-component dicarbofunctionalization reactions involving radical capture by nickel

S Zhu, X Zhao, H Li, L Chu - Chemical Society Reviews, 2021 - pubs.rsc.org
The catalytic dicarbofunctionalization of unsaturated π bonds represents a powerful platform
for the rapid construction of complex motifs. Despite remarkable progress, novel and efficient …

Anti-Markovnikov intermolecular hydroamination of alkenes and alkynes: a mechanistic view

J Escorihuela, A Lledós, G Ujaque - Chemical Reviews, 2023 - ACS Publications
Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

Nitrene transfer and carbene transfer in gold catalysis

LW Ye, XQ Zhu, RL Sahani, Y Xu, PC Qian… - Chemical …, 2020 - ACS Publications
Catalytic transformations involving metal carbenes are considered one of the most important
aspects of homogeneous transition metal catalysis. Recently, gold-catalyzed generation of …

Divergent gold catalysis: unlocking molecular diversity through catalyst control

CC Chintawar, AK Yadav, A Kumar… - Chemical …, 2021 - ACS Publications
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

Optimization of catalysts and conditions in gold (I) catalysis—counterion and additive effects

Z Lu, T Li, SR Mudshinge, B Xu… - Chemical …, 2021 - ACS Publications
Gold catalysis has proven to be an important breakthrough for organic synthesis. The
tunable nature of gold catalysts, the unique properties of gold, and the mild reaction …

Expanding the synthetic toolbox through metal–enzyme cascade reactions

S González-Granda, J Albarrán-Velo… - Chemical …, 2023 - ACS Publications
The combination of metal-, photo-, enzyme-, and/or organocatalysis provides multiple
synthetic solutions, especially when the creation of chiral centers is involved. Historically …

The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds

VW Bhoyare, AG Tathe, A Das, CC Chintawar… - Chemical Society …, 2021 - pubs.rsc.org
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Photoredox catalysis in organic chemistry

MH Shaw, J Twilton… - The Journal of organic …, 2016 - ACS Publications
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a
powerful strategy for the activation of small molecules. In a general sense, these approaches …

Gold-catalyzed synthesis of small rings

M Mato, A Franchino, C Garcı́a-Morales… - Chemical …, 2020 - ACS Publications
Three-and four-membered rings, widespread motifs in nature and medicinal chemistry, have
fascinated chemists ever since their discovery. However, due to energetic considerations …