A general method to describe intersystem crossing dynamics in trajectory surface hopping

S Mai, P Marquetand, L González - International Journal of …, 2015 - Wiley Online Library
Intersystem crossing is a radiationless process that can take place in a molecule irradiated
by UV‐Vis light, thereby playing an important role in many environmental, biological and …

Poly (Vinyl Ketones): New Directions in Photodegradable Polymers

D Pal, D Konar, BS Sumerlin - Macromolecular Rapid …, 2023 - Wiley Online Library
Abstract Poly (vinyl ketones)(PVKs) have received considerable attention over the past few
decades due to their unique photochemistry and photodegradation properties under …

Photochemical action plots reveal the fundamental mismatch between absorptivity and photochemical reactivity

SL Walden, JA Carroll, AN Unterreiner… - Advanced …, 2024 - Wiley Online Library
Over the last years, the authors' laboratory has employed monochromatic tuneable laser
systems to reveal a fundamental mismatch between the absorptivity of a chromophore and …

Search for alternative two‐step‐absorption photoinitiators for 3D laser nanoprinting

NM Bojanowski, A Vranic, V Hahn… - Advanced Functional …, 2023 - Wiley Online Library
Recent studies have opened the door to a new generation of photoinitiators for 3D laser
nanoprinting. Therein, the simultaneous absorption of two photons, commonly referred to as …

Design, synthesis and properties of carbazole-indenedione based photobleachable photoinitiators for photopolymerization

W Liao, Q Liao, Y Xiong, Z Li, H Tang - Journal of Photochemistry and …, 2023 - Elsevier
In order to investigate the properties of carbazole-indenedione based photoinitiators for
photopolymerization, two visible light-sensitive photoinitiators (CAs) were designed and …

Novel multifunctional unimolecular initiators built on natural indole featuring fast photobleaching and visible light/thermal double polymerization

S Gong, X Wu, Q Liao, S Deng, J Hou, K Tang… - Green …, 2023 - pubs.rsc.org
Four asymmetric D–π-A–π-A′ visible light initiators (IDs) were synthesized with indole as
the electron donor (D), and the carbonyl group and oxime ester as the first and second …

Choosing the ideal photoinitiator for free radical photopolymerizations: predictions based on simulations using established data

A Eibel, DE Fast, G Gescheidt - Polymer Chemistry, 2018 - pubs.rsc.org
We present a tool for predicting the initiation efficiency of various type 1 (α-cleavage)
photoinitiators for free radical photopolymerization. The amount of initiated polymer chains is …

Ultrafast intersystem crossing dynamics in uracil unravelled by ab initio molecular dynamics

M Richter, S Mai, P Marquetand… - Physical Chemistry …, 2014 - pubs.rsc.org
Ab initio molecular dynamics simulations have been performed in order to investigate the
relaxation dynamics of uracil after UV excitation in gas phase. Intersystem crossing (ISC) …

Remote effect of substituents on the properties of phenyl thienyl thioether-based oxime esters as LED-sensitive photoinitiators

W Wang, M Jin, H Pan, D Wan - Dyes and Pigments, 2021 - Elsevier
Visible light-sensitive photoinitiators (PIs) are essential for light-emitting diode (LED)
photopolymerization as LEDs are becoming the predominant light sources. In this work, five …

Electrostatically tuning the photodissociation of the Irgacure 2959 photoinitiator in the gas phase by cation binding

SJP Marlton, BI McKinnon, NS Hill… - Journal of the …, 2021 - ACS Publications
The low-lying electronic states of Irgacure 2959, a Norrish-type I photoinitiator, complexed
with a single metal cation are investigated in the gas phase by photodissociation action …