Formic acid as a hydrogen source–recent developments and future trends

M Grasemann, G Laurenczy - Energy & Environmental Science, 2012 - pubs.rsc.org
Formic acid has recently been suggested as a promising hydrogen storage material. The
basic concept is briefly discussed and the recent advances in the development of formic acid …

Molybdenum carbide as alternative catalyst for hydrogen production–A review

Y Ma, G Guan, X Hao, J Cao, A Abudula - Renewable and Sustainable …, 2017 - Elsevier
Hydrogen energy has become an important research area worldwide for environmental-
friendly and sustainable energy development. A large number of studies can be found in the …

Modulating oxygen coverage of Ti3C2Tx MXenes to boost catalytic activity for HCOOH dehydrogenation

T Hou, Q Luo, Q Li, H Zu, P Cui, S Chen, Y Lin… - Nature …, 2020 - nature.com
As a promising hydrogen carrier, formic acid (HCOOH) is renewable, safe and nontoxic.
Although noble-metal-based catalysts have exhibited excellent activity in HCOOH …

Selective hydrogen production from formic acid decomposition on Pd–Au bimetallic surfaces

WY Yu, GM Mullen, DW Flaherty… - Journal of the American …, 2014 - ACS Publications
Pd–Au catalysts have shown exceptional performance for selective hydrogen production via
HCOOH decomposition, a promising alternative to solve issues associated with hydrogen …

Structure and surface chemistry of gold-based model catalysts

J Gong - Chemical reviews, 2012 - ACS Publications
Gold ([Xe] 4f 14 5d 10 6s 1) is one of the most ancient themes of investigation in science and
arts, and its renaissance now leads to an exponentially increasing number of publications …

Reaction mechanism of vapor-phase formic acid decomposition over platinum catalysts: DFT, reaction kinetics experiments, and microkinetic modeling

S Bhandari, S Rangarajan, CT Maravelias… - Acs …, 2020 - ACS Publications
A combination of periodic density functional theory (DFT, PW91-GGA) calculations, reaction
kinetics experiments, and mean-field microkinetic modeling is used to derive insights on the …

Reactions of water and C1 molecules on carbide and metal-modified carbide surfaces

W Wan, BM Tackett, JG Chen - Chemical Society Reviews, 2017 - pubs.rsc.org
The formation of carbides can significantly modify the physical and chemical properties of
the parent metals. In the current review, we summarize the general trends in the reactions of …

Formic acid decomposition on Au catalysts: DFT, microkinetic modeling, and reaction kinetics experiments

S Singh, S Li, R Carrasquillo‐Flores… - AIChE …, 2014 - Wiley Online Library
A combined theoretical and experimental approach is presented that uses a comprehensive
mean‐field microkinetic model, reaction kinetics experiments, and scanning transmission …

Experimental and computational investigation of acetic acid deoxygenation over oxophilic molybdenum carbide: surface chemistry and active site identity

JA Schaidle, J Blackburn, CA Farberow, C Nash… - ACS …, 2016 - ACS Publications
Ex situ catalytic fast pyrolysis (CFP) is a promising route for producing fungible biofuels;
however, this process requires bifunctional catalysts that favor C–O bond cleavage, activate …

Elementary steps of syngas reactions on Mo2C (0 0 1): Adsorption thermochemistry and bond dissociation

AJ Medford, A Vojvodic, F Studt, F Abild-Pedersen… - Journal of catalysis, 2012 - Elsevier
Density functional theory (DFT) and ab initio thermodynamics are applied in order to
investigate the most stable surface and subsurface terminations of Mo2C (001) as a function …