In the last few years, considerable progress has been made in the synthesis of C-glycosides.
Despite its challenging chemistry, due to its versatility, C-glycosides play a pivotal role in …

Homogeneous catalysis plays an important and ubiquitous role in the synthesis of simple
and complex molecules, including drug compounds, natural products, and agrochemicals. In …

The importance of carbohydrate chemistry in biological and medicinal chemistry has led to
enormous developments in the synthesis of carbohydrate mimics. In this context, the …

Methods of the synthesis and the investigation of the properties of unnatural seven-
memebered cyclic sugars and nucleosides, are of high interest. Septanoses provide …

Oxepanes are central motifs and tenants of many biologically important molecules, and their
synthetic construction often presents a challenge to chemists due to consequential entropic …

Addition of a carbene to a glycal is the prominent method for the synthesis of 1, 2-
cyclopropyl carbohydrates. This incorporation of a cyclopropane into a carbohydrate scaffold …

A kinetic study of the hydrolytic stabilities of mono-, di-, and 2-chloro-2-deoxy septanosides,
under acid-catalysis, is reported herein. A comparison of mono-and diseptanosides, shows …

Abstract Treatment of gem-dihalo-1, 2-cyclopropanated d-oxyglycal with primary, secondary,
and unsaturated alcohols, in the presence of AgOAc, leads to the formation of chloro …

In the presence of a nucleophilic base, ring-fused gem-dibromocyclopropanes derived from
d-glycals undergo ring opening to give 2-deoxy-2-(E-bromomethylene) glycosides. Such …

Abstract The ring opening of 1, 2-(gem-dibromo) cyclopropyl carbohydrates by two different
modes leads to either 2-C-(bromomethylene) pyranosides (using base) or 2-bromooxepines …