Recent developments in β-C-glycosides: synthesis and applications
K Lalitha, K Muthusamy, YS Prasad, PK Vemula… - Carbohydrate …, 2015 - Elsevier
In the last few years, considerable progress has been made in the synthesis of C-glycosides.
Despite its challenging chemistry, due to its versatility, C-glycosides play a pivotal role in …
Despite its challenging chemistry, due to its versatility, C-glycosides play a pivotal role in …
Homogeneous catalysis: a powerful technology for the modification of important biomolecules
YG Shelke, A Yashmeen, AVA Gholap… - Chemistry–An Asian …, 2018 - Wiley Online Library
Homogeneous catalysis plays an important and ubiquitous role in the synthesis of simple
and complex molecules, including drug compounds, natural products, and agrochemicals. In …
and complex molecules, including drug compounds, natural products, and agrochemicals. In …
Recent Developments in the Synthesis of 2‐C‐Branched and 1,2‐Annulated Carbohydrates
YD Vankar, T Linker - European Journal of Organic Chemistry, 2015 - Wiley Online Library
The importance of carbohydrate chemistry in biological and medicinal chemistry has led to
enormous developments in the synthesis of carbohydrate mimics. In this context, the …
enormous developments in the synthesis of carbohydrate mimics. In this context, the …
Unusual seven-membered ring sugars and nucleosides: synthesis and biological properties
S Manta, N Kollatos - Nucleosides, Nucleotides & Nucleic Acids, 2023 - Taylor & Francis
Methods of the synthesis and the investigation of the properties of unnatural seven-
memebered cyclic sugars and nucleosides, are of high interest. Septanoses provide …
memebered cyclic sugars and nucleosides, are of high interest. Septanoses provide …
Advancements in the Synthesis of Polyoxygenated Oxepanes and Thiepanes for Applications to Natural Products
Oxepanes are central motifs and tenants of many biologically important molecules, and their
synthetic construction often presents a challenge to chemists due to consequential entropic …
synthetic construction often presents a challenge to chemists due to consequential entropic …
Reactions of 1, 2-cyclopropyl carbohydrates
Addition of a carbene to a glycal is the prominent method for the synthesis of 1, 2-
cyclopropyl carbohydrates. This incorporation of a cyclopropane into a carbohydrate scaffold …
cyclopropyl carbohydrates. This incorporation of a cyclopropane into a carbohydrate scaffold …
Glycosidic bond hydrolysis in septanosides: a comparison of mono-, di-, and 2-chloro-2-deoxy-septanosides
S Dey, N Jayaraman - Carbohydrate research, 2014 - Elsevier
A kinetic study of the hydrolytic stabilities of mono-, di-, and 2-chloro-2-deoxy septanosides,
under acid-catalysis, is reported herein. A comparison of mono-and diseptanosides, shows …
under acid-catalysis, is reported herein. A comparison of mono-and diseptanosides, shows …
Exclusive ring opening of gem-dihalo-1, 2-cyclopropanated oxyglycal to oxepines in AgOAc
S Dey, N Jayaraman - Carbohydrate research, 2014 - Elsevier
Abstract Treatment of gem-dihalo-1, 2-cyclopropanated d-oxyglycal with primary, secondary,
and unsaturated alcohols, in the presence of AgOAc, leads to the formation of chloro …
and unsaturated alcohols, in the presence of AgOAc, leads to the formation of chloro …
Mechanistic Studies on the Base-Promoted Ring Opening of Glycal-Derived gem-Dibromocyclopropanes
RJ Lepage, PW Moore, RJ Hewitt… - The Journal of …, 2021 - ACS Publications
In the presence of a nucleophilic base, ring-fused gem-dibromocyclopropanes derived from
d-glycals undergo ring opening to give 2-deoxy-2-(E-bromomethylene) glycosides. Such …
d-glycals undergo ring opening to give 2-deoxy-2-(E-bromomethylene) glycosides. Such …
Divergent synthesis of 2-C-branched pyranosides and oxepines from 1, 2-gem-dibromocyclopropyl carbohydrates
Abstract The ring opening of 1, 2-(gem-dibromo) cyclopropyl carbohydrates by two different
modes leads to either 2-C-(bromomethylene) pyranosides (using base) or 2-bromooxepines …
modes leads to either 2-C-(bromomethylene) pyranosides (using base) or 2-bromooxepines …