Metal tetraoxygen molecules (MO4, M= Fe, Ru, Os, Hs, Sm, Pu) of all metal atoms M with
eight valence electrons are theoretically studied using density functional and correlated …

The use of neat fluorine in matrix isolation is reported, as well as the formation of
polyfluoride monoanions under cryogenic conditions. Purification procedures and …

The tendency of high-valence xenon to form consolidated oxide structures is herein
supported by the study of K4Xe3O12, the first example of a layered xenon perovskite. Xenon …

We have developed a new database of structures and bond energies of 59 noble‐gas‐
containing molecules. The structures were calculated by CCSD (T)/aug‐cc‐pVTZ methods …

The [XeOXeOXe] 2+ cation provides an unprecedented example of a xenon (II) oxide and a
noble-gas oxocation as well as a rare example of a noble-gas dication. The [XeOXeOXe] 2+ …

A quantum chemical survey of radon and xenon tetroxides (NgO4, Ng= Xe, Rn) is reported
herein. The intermediate species, which are formed in their explosive decomposition back to …

This work theoretically investigates the novel family of multi-coordinated noble gas (Ng)
complexes Xe (AuF) n (n= 2–4). Geometrical optimization at the LC-ωPBE-D3/def2TZVPP …

Abstract Acetonitrile and [FXeOXe‐‐‐FXeF][AsF6] react at− 60° C in anhydrous HF (aHF) to
form the CH3CN adduct of the previously unknown [XeOXe] 2+ cation. The low‐temperature …

The elements of group 18 (the noble gases) are, generally, perceived as only less reactive.
Only krypton and xenon form, in fact, isolable compounds (the radioactive and short-lived …

Abstract Hauptgruppenelemente: Carbonylverbindungen eines p‐Blockelements, ein
Lewispaar, in dem Phosphor gleich doppelt frustriert ist, die erste Kristallstruktur eines …