In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …

Catalytic hydrogen atom transfer from metal‐hydrides to alkenes allows feedstock olefins to
be used as alkyl radical precursors. The chemoselectivity of this process makes it an …

The current status of homogeneous iron catalysis in organic chemistry is contemplated, as
are the reasons why this particular research area only recently starts challenging the …

This Article details the development of the iron-catalyzed conversion of olefins to radicals
and their subsequent use in the construction of C–C bonds. Optimization of a reductive …

Due to their strong dependence on local atonic environments, NMR chemical shifts are
among the most powerful tools for strucutre elucidation of powdered solids or amorphous …

A combination of cobalt and nickel catalytic cycles enables a highly branch-selective
(Markovnikov) olefin hydroarylation. Radical cyclization and ring scission experiments are …

Hydrogen atom transfer (HAT) hydrogenation has recently emerged as an indispensable
method for the chemoselective reduction of unactivated alkenes. However, the hitherto …

First-row transition-metal-mediated reactions constitute an important and growing area of
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …