Organic synthesis using nitroxides

D Leifert, A Studer - Chemical Reviews, 2023 - ACS Publications
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Innovative electrochemical strategies for hydrogen production: From electricity input to electricity output

D Yan, C Mebrahtu, S Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Renewable H2 production by water electrolysis has attracted much attention due to its
numerous advantages. However, the energy consumption of conventional water electrolysis …

Unraveling the mechanism for paired electrocatalysis of organics with water as a feedstock

G Yang, Y Jiao, H Yan, Y Xie, C Tian, A Wu… - Nature …, 2022 - nature.com
Paired electroreduction and electrooxidation of organics with water as a feedstock to
produce value-added chemicals is meaningful. A comprehensive understanding of reaction …

Regulating the d-band center of metal–organic frameworks for efficient nitrate reduction reaction and zinc-nitrate battery

Y Yao, X Wei, H Zhou, K Wei, B Kui, F Wu, L Chen… - ACS …, 2024 - ACS Publications
The electrochemical reduction of nitrate ions to valuable ammonia enables the recovery of
nitrate pollutants from industrial wastewater, thereby synchronously balancing the nitrogen …

Electro‐synthesis of organic compounds with heterogeneous catalysis

T Ali, H Wang, W Iqbal, T Bashir, R Shah… - Advanced …, 2023 - Wiley Online Library
Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science,
medicinal chemistry, and future industrial applications in energy storage and conversion. To …

Selenium vacancies regulate d-band centers in Ni3Se4 toward paired electrolysis in anion-exchange membrane electrolyzers for upgrading N-containing …

F Yue, C Wang, W Duan, H Pang, T Wei, K Xue… - Science China …, 2023 - Springer
Paired electrolysis in anion-exchange membrane (AEM) electrolyzers toward the cathodic
nitrate reduction reaction (NO3RR) and anodic benzylamine oxidation reaction (BOR) could …

Electrochemical hydrogenation and oxidation of organic species involving water

C Liu, F Chen, BH Zhao, Y Wu, B Zhang - Nature Reviews Chemistry, 2024 - nature.com
Fossil fuel-driven thermochemical hydrogenation and oxidation using high-pressure H2 and
O2 are still popular but energy-intensive CO2-emitting processes. At present, developing …

[HTML][HTML] Recent progress in advanced catalysts for electrocatalytic hydrogenation of organics in aqueous conditions

Y Zeng, M Zhao, H Zeng, Q Jiang, F Ming, K Xi, Z Wang… - Escience, 2023 - Elsevier
Electrocatalytic hydrogenation (ECH) of organics using water as hydrogen donors has been
regarded as a green organic reduction technique to replace traditional chemical reactions …

Ni–Co Alloy Nanoparticles Catalyze Selective Electrochemical Coupling of Nitroarenes into Azoxybenzene Compounds in Aqueous Electrolyte

W Gong, X Mao, J Zhang, Y Lin, H Zhang, A Du… - ACS …, 2023 - ACS Publications
In theory, electrocatalysts in their metallic forms should be the most stable chemical state
under cathodic potentials. It is known that the highly dispersed nanoparticle (NP) types of …

Self-supported nanoporous CuNiAl alloy as highly efficient electrocatalyst for nitrobenzene hydrogenation to aniline

R Yao, Y Li, X Zhang, Y Zhao, Y Wang, X Lang… - Chemical Engineering …, 2023 - Elsevier
Electrocatalytic nitrobenzene (NB) hydrogenation with high selectivity, yield and Faradaic
efficiency (FE) is an economic and sustainable approach to produce high-purity aniline (BA) …