Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded
as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes …

In this contribution, the latest developments in solid state NMR are presented in the field of
organic–inorganic (O/I) materials (or hybrid materials). Such materials involve mineral and …

Determination of the aggregation and solvation numbers of organometallic complexes in
solution is an important task to increase insight in reaction mechanisms. Thus knowing …

Diffusion-ordered spectroscopy (DOSY), which separates NMR signals according to
diffusion coefficient, is finding increasing use for the analysis of mixtures of small-to medium …

To address the practical issues of polymer molecular weight determination, the first accurate
polymer weight-average molecular weight determination method in diverse living/controlled …

Reliable structure elucidation of covalent organic cage compounds remains challenging as
routine analysis might leave ambiguities. Diffusion‐ordered NMR spectroscopy (DOSY) …

Here we report the formation of giant {Mo126W30} polyoxometalate cages templated by π‐
conjugated planar ligands. Their inorganic shells incorporate arrays of 18 stacked aromatic …

The efficient and selective organozirconium (IV)-mediated, intermolecular hydrothiolation of
terminal alkynes by aliphatic, benzylic, and aromatic thiols using CGCZrMe2 (CGC …

A potential advantage of platelet-like nanofillers as nanocomposite reinforcements is the
possibility of achieving two-dimensional stiffening through planar orientation of the platelets …

This paper deals with the synthesis, structural studies, and behavior in solution of
unprecedented coordination complexes built by the association of a panel of 14 …