This review is a comprehensive survey of the last 10 years of research on ammonia–borane
and amine–borane dehydrogenation mediated by complex metal hydrides (CMHs), within …

Mechanistic studies into the catalysed dehydrocoupling of amine–boranes and phosphine–
boranes have seen a rapid development over the last 5 years. The primary driver for this …

The following article is based on the MRS Medal talk presented by William L. Johnson at the
1998 MRS Fall Meeting on December 2, 1998. The MRS Medal is awarded for a specific …

This study details the first use of well-defined low-valent p-block metal hydrides as catalysts
in organic synthesis. That is, the bulky, two-coordinate germanium (II) and tin (II) hydride …

The synthesis of N-heterocycles is of paramount importance for the pharmaceutical industry.
They are often synthesized through atom economic and environmentally unfriendly …

A detailed catalytic, stoichiometric, and mechanistic study on the dehydrocoupling of H3B·
NMe2H and dehydropolymerization of H3B· NMeH2 using the [Rh (Xantphos)]+ fragment is …

A systematic study of the catalyst structure and overall charge for the dehydropolymerization
of H3B· NMeH2 to form N-methyl polyaminoborane is reported using catalysts based upon …

Herein, we report the preparation and characterization of platinum (0) nanoparticles
stabilized by amylamine (C5H11NH2) ligands plus their catalytic use in the room …

The air tolerant precatalyst,[Rh (L)(NBD)] Cl ([1] Cl)[L= κ3-(i Pr2PCH2CH2) 2NH, NBD=
norbornadiene], mediates the selective synthesis of N-methylpolyaminoborane,(H2BNMeH) …

Coordinatively unsaturated Pt (II) complex [Pt (I t Bu′)(I t Bu)]+ stabilized by N-heterocyclic
carbene (NHC) ligands dehydrogenates N, N-dimethylamineborane through a mechanism …