Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

DW Stephan, G Erker - Chemical Science, 2014 - pubs.rsc.org
Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …

Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven

DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

Frustrated Lewis pairs: bonding, reactivity, and applications

M Ghara, H Mondal, R Pal… - The Journal of Physical …, 2023 - ACS Publications
The outstanding capability of Frustrated Lewis Pair (FLP) catalysts to activate small
molecules has gained significant attention in recent times. Reactivity of FLP is further …

Element‐Ligand Cooperativity with p‐Block Elements

L Greb, F Ebner, Y Ginzburg… - European Journal of …, 2020 - Wiley Online Library
Metal‐ligand cooperativity (MLC) had a tremendous impact on d‐block metal‐mediated
bond activation and homogeneous catalysis. Is this concept translatable to the elements of …

Activation of Small Molecules and Hydrogenation of CO2 Catalyzed by Frustrated Lewis Pairs

R Pal, M Ghara, PK Chattaraj - Catalysts, 2022 - mdpi.com
The chemistry of frustrated Lewis pair (FLP) is widely explored in the activation of small
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …

Carbonylation reactions of intramolecular vicinal frustrated phosphane/borane Lewis pairs

M Sajid, A Lawzer, W Dong, C Rosorius… - Journal of the …, 2013 - ACS Publications
The intramolecular frustrated Lewis pair (FLP) Mes2PCH2CH2B (C6F5) 2 4 adds
cooperatively to carbon monoxide to form the five-membered heterocyclic carbonyl …

Frustrated Lewis pair chemistry: Searching for new reactions

G Kehr, G Erker - The Chemical Record, 2017 - Wiley Online Library
Frustrated Lewis pair chemistry has taken a steep development in the recent years. It offers
possibilities of developing new variants of known reactions and of finding new chemical …

Advanced 1, 1-carboboration reactions with pentafluorophenylboranes

G Kehr, G Erker - Chemical Science, 2016 - pubs.rsc.org
The 1, 1 carboboration reaction of a variety of metal-substituted alkynes with simple
trialkylboranes R3B yields the respective alkenylboranes (Wrackmeyer reaction). The use of …

Reaction of B2(o‐tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations

Y Katsuma, N Tsukahara, L Wu, Z Lin… - Angewandte Chemie …, 2018 - Wiley Online Library
The reaction of highly Lewis acidic tetra (o‐tolyl) diborane (4) with CO afforded a mixture of
boraindane and boroxine by the cleavage of the C≡ O triple bond. 13C labeling …