Frustrated Lewis pair chemistry: development and perspectives
DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …
solution that are deterred from strong adduct formation by steric and/or electronic factors …
Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides
DW Stephan, G Erker - Chemical Science, 2014 - pubs.rsc.org
Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …
Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven
DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …
Frustrated Lewis pairs: bonding, reactivity, and applications
The outstanding capability of Frustrated Lewis Pair (FLP) catalysts to activate small
molecules has gained significant attention in recent times. Reactivity of FLP is further …
molecules has gained significant attention in recent times. Reactivity of FLP is further …
Element‐Ligand Cooperativity with p‐Block Elements
Metal‐ligand cooperativity (MLC) had a tremendous impact on d‐block metal‐mediated
bond activation and homogeneous catalysis. Is this concept translatable to the elements of …
bond activation and homogeneous catalysis. Is this concept translatable to the elements of …
Activation of Small Molecules and Hydrogenation of CO2 Catalyzed by Frustrated Lewis Pairs
The chemistry of frustrated Lewis pair (FLP) is widely explored in the activation of small
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …
Carbonylation reactions of intramolecular vicinal frustrated phosphane/borane Lewis pairs
M Sajid, A Lawzer, W Dong, C Rosorius… - Journal of the …, 2013 - ACS Publications
The intramolecular frustrated Lewis pair (FLP) Mes2PCH2CH2B (C6F5) 2 4 adds
cooperatively to carbon monoxide to form the five-membered heterocyclic carbonyl …
cooperatively to carbon monoxide to form the five-membered heterocyclic carbonyl …
Frustrated Lewis pair chemistry: Searching for new reactions
G Kehr, G Erker - The Chemical Record, 2017 - Wiley Online Library
Frustrated Lewis pair chemistry has taken a steep development in the recent years. It offers
possibilities of developing new variants of known reactions and of finding new chemical …
possibilities of developing new variants of known reactions and of finding new chemical …
Advanced 1, 1-carboboration reactions with pentafluorophenylboranes
G Kehr, G Erker - Chemical Science, 2016 - pubs.rsc.org
The 1, 1 carboboration reaction of a variety of metal-substituted alkynes with simple
trialkylboranes R3B yields the respective alkenylboranes (Wrackmeyer reaction). The use of …
trialkylboranes R3B yields the respective alkenylboranes (Wrackmeyer reaction). The use of …
Reaction of B2(o‐tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations
Y Katsuma, N Tsukahara, L Wu, Z Lin… - Angewandte Chemie …, 2018 - Wiley Online Library
The reaction of highly Lewis acidic tetra (o‐tolyl) diborane (4) with CO afforded a mixture of
boraindane and boroxine by the cleavage of the C≡ O triple bond. 13C labeling …
boraindane and boroxine by the cleavage of the C≡ O triple bond. 13C labeling …