Carbohydrates, which are ubiquitously distributed throughout the three domains of life, play
significant roles in a variety of vital biological processes. Access to unique and …

Publisher Summary This chapter analyzes the importance of thioclycosides as the glycosyl
donors in oligosaccharide synthesis. The presence and biological importance of …

Carbohydrates are diverse bio-macromolecules with highly complex structures that are
involved in numerous biological processes. Well-defined carbohydrates obtained by …

Glycans are involved in various life processes and represent critical targets of biomedical
developments. Nevertheless, the accessibility to long glycans with precise structures …

The efficient synthesis of long, branched, and complex carbohydrates containing multiple 1,
2‐cis glycosidic linkages is a long‐standing challenge. Here, we report a merging reagent …

Polysaccharides are the most abundant organic materials in nature, yet correlations
between their three-dimensional structure and macroscopic properties have not been …

Here we summarize the chemical syntheses of glycans containing over 20 monosaccharide
units, with the recent syntheses of ultra-long glycans, including a 92mer arabinogalactan, a …

The aim of this review is to discuss the accomplishments made in the area of the
stereoselective formation of a 1, 2-cis glycosidic bond. Importance of this subject derives …

This Review describes the basic concepts that have guided our exploration of new chemical
reactions by giving examples of results from my research group. Our strategy of carrying out …

Stereocontrolled Glycosyl Transfer Reactions with Unprotected Glycosyl Donors | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …