Polyfluorinated ethanes as versatile fluorinated C2-building blocks for organic synthesis

VG Nenajdenko, VM Muzalevskiy, AV Shastin - Chemical reviews, 2015 - ACS Publications
Fluorinated compounds attracted remarkable interest in recent decades. 1 Unique complex
of physicochemical and biological properties provided by incorporation of fluorine or …

An overview of the synthesis of alkenylphosphines

D Julienne, O Delacroix… - Current Organic …, 2010 - ingentaconnect.com
Alkenylphosphines are compounds of great interest in view of their structures. Hence, these
phosphorus derivatives bear a carbon-carbon double bond, directly linked to the …

Structural aspect of platinum coordination compounds: Part III. Monomeric square planar (Pt A2XY and PtABXY) and Trigonal Bipyramidal PtII coordination …

CE Holloway, M McInik - Reviews in Inorganic Chemistry, 2004 - degruyter.com
The chemistry of platinum-is particularly important in the areas of catalysis and biochemistry.
In our previous reviews we dealt with two-, threeand four-coordinate PtXi derivatives (450 …

Organomonophosphines in PtP2Cl2 derivatives: structural aspects

M Melník, P Mikuš - Reviews in Inorganic Chemistry, 2015 - degruyter.com
In this review, 260 monomeric Pt (II) complexes are summarized and analyzed in which the
inner coordination sphere is built up by a pair of organomonophosphines and two chlorine …

Hydrofluorocarbon 245fa: a versatile new synthon in alkyne chemistry

AK Brisdon, IR Crossley - Chemical communications, 2002 - pubs.rsc.org
Hydrofluorocarbon 245fa: a versatile new synthon in alkyne chemistry - Chemical
Communications (RSC Publishing) DOI:10.1039/B207979H Royal Society of Chemistry View …

Spectroscopic and structural assignment of the absolute stereochemistry in a series of 1, 2-difluorovinyl organometalloids. The first crystallographic characterization …

AK Brisdon, IR Crossley, RG Pritchard… - Inorganic …, 2002 - ACS Publications
The group 14 trifluorovinyl compounds Ph3ECF CF2 (E= Ge, Sn, Pb) have been prepared in
high yield by the low-temperature reaction of the triphenylelement halide with …

Recent advances in fluorovinyl-containing compounds

NA Barnes, AK Brisdon, MJ Ellis… - Journal of Fluorine …, 2001 - Elsevier
The reaction of the HFC-replacements CF3CH2F (HFC-134a) and CF3CH2Cl (HCFC-133a)
with two equivalents of butyllithium generates, in high yield, the fluorovinyllithium reagents …

Synthesis of gold (I) fluoroalkyl and fluoroalkenyl-substituted phosphine complexes and factors affecting their crystal packing

NA Barnes, AK Brisdon, FRW Brown, WI Cross… - Dalton …, 2011 - pubs.rsc.org
A series of gold (I) phosphine complexes of the type [AuCl {PR2 (Rf)}](R= Et, i-Pr, Cy; Rf=
CFCF2; R= Ph, Rf= CFCFH, CClCF2, CCCF3, CF3, i-C3F7, s-C4F9) have been prepared …

The synthesis and chemistry of fluorovinyl-containing phosphines and the single crystal X-ray structure of SPPr i2 (CF [double bond, length as m-dash] CF 2)

NA Barnes, AK Brisdon, FRW Brown, WI Cross… - New Journal of …, 2004 - pubs.rsc.org
The first perfluorovinyl alkyl-containing phosphines of the type PR2 (CFCF2)(R= Et, iPr, Cy)
are reported. The reactivity of these air-and moisture-stable materials has been explored …

Experimental and Theoretical Studies of Bis(perfluorovinyl)mercury, Hg(CF=CF2)2: Synthesis, Characterization, and Structure in the Gaseous and Crystalline …

KK Banger, AK Brisdon, PT Brain, S Parsons… - Inorganic …, 1999 - ACS Publications
The low-temperature reaction between 2 equiv of (perfluorovinyl) lithium, derived from
CF3CH2F and butyllithium, and mercury (II) chloride results in high yields of Hg (CF CF2) 2 …