Nickel hydride complexes
NA Eberhardt, H Guan - Chemical reviews, 2016 - ACS Publications
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
Catalytic asymmetric conjugate reduction
G Lonardi, R Parolin, G Licini… - Angewandte Chemie …, 2023 - Wiley Online Library
Enantioselective reduction reactions are privileged transformations for the construction of
trisubstituted stereogenic centers. While these include established synthetic strategies, such …
trisubstituted stereogenic centers. While these include established synthetic strategies, such …
Non-precious metal complexes with an anionic PCP pincer architecture
S Murugesan, K Kirchner - Dalton Transactions, 2016 - pubs.rsc.org
This perspective article provides an overview of the advancements in the field of non-
precious metal complexes featuring anionic PCP pincer ligands with the inclusion of …
precious metal complexes featuring anionic PCP pincer ligands with the inclusion of …
Thermally robust and highly active pcp cobalt (II) catalyst for linear-selective hydroboration of terminal and internal olefins
J Liu, J Du, F Yu, L Gan, G Liu, Z Huang - ACS Catalysis, 2023 - ACS Publications
We report the design and synthesis of cobalt complexes of L2X-type ligands for olefin
hydroboration guided by the consideration of catalyst stability. Among the series of PCP …
hydroboration guided by the consideration of catalyst stability. Among the series of PCP …
Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co (iii) complexes and initial hydroboration trials
Development of CCC-NHC pincer Co complexes via transmetalation from Zr is reported.
Formation of these air-stable Co (III) complexes was achieved through use of a CoCl2 or Co …
Formation of these air-stable Co (III) complexes was achieved through use of a CoCl2 or Co …
Monoanionic bis (carbene) pincer complexes featuring cobalt (I–III) oxidation states
AD Ibrahim, K Tokmic, MR Brennan, D Kim… - Dalton …, 2016 - pubs.rsc.org
The synthesis and characterization of a series of cobalt complexes featuring a pincer bis
(carbene) ligand of the meta-phenylene-bridged bis-N-heterocyclic carbene (ArCCC, Ar= 2 …
(carbene) ligand of the meta-phenylene-bridged bis-N-heterocyclic carbene (ArCCC, Ar= 2 …
Cobalt POCOP Pincer Complexes via Ligand C–H Bond Activation with Co2(CO)8: Catalytic Activity for Hydrosilylation of Aldehydes in an Open vs a Closed System
A series of cobalt POCOP pincer complexes with the formulas {2, 6-(iPr2PO) 2-4-R′-C6H2}
Co (CO) 2 (R′= H (1a), NMe2 (1b), OMe (1c), CO2Me (1d)),{2, 6-(Ph2PO) 2C6H3} Co (CO) …
Co (CO) 2 (R′= H (1a), NMe2 (1b), OMe (1c), CO2Me (1d)),{2, 6-(Ph2PO) 2C6H3} Co (CO) …
C (sp)–H, S–H, and Sn–H Bond Activation with a Cobalt (I) Pincer Complex
This study focuses on the stoichiometric reactions of {2, 6-(i Pr2PO) 2C6H3} Co (PMe3) 2
with terminal alkynes, thiols, and tin hydrides as part of an effort to develop catalytic, two …
with terminal alkynes, thiols, and tin hydrides as part of an effort to develop catalytic, two …
Hard to Handle: Extremely Labile Hydrido Nickel(II) Complexes of Cyclometalated C∧N∧N and N∧C∧N Ligands
L Kletsch, L Payen, A Fiorentino, B Blom… - …, 2023 - ACS Publications
From the two organonickel (II) scaffolds [Ni (Phbpy)]+ and [Ni (PyPhPy)]+(HPhbpy= 6-phenyl-
2, 2′-bipyridine≡ HC∧ N∧ N and Py (HPh) Py= 2, 6-di-2-pyridyl-benzene≡ N∧(HC)∧ …
2, 2′-bipyridine≡ HC∧ N∧ N and Py (HPh) Py= 2, 6-di-2-pyridyl-benzene≡ N∧(HC)∧ …
Which Type of Pincer Complex Is Thermodynamically More Stable? Understanding the Structures and Relative Bond Strengths of Group 10 Metal Complexes …
The influence of the pincer platform composition and substitution on the reactivity and
physical properties of pincer complexes can be easily explored through different …
physical properties of pincer complexes can be easily explored through different …