Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design
Y Zhao, DP Adiyeri Saseendran, C Huang… - Chemical …, 2023 - ACS Publications
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of
various energy conversion and storage systems. However, their sluggish reaction kinetics …
various energy conversion and storage systems. However, their sluggish reaction kinetics …
Progress and prospects in nonlinear extreme-ultraviolet and X-ray optics and spectroscopy
Free-electron lasers and high-harmonic-generation table-top systems are new sources of
extreme-ultraviolet to hard X-ray photons, providing ultrashort pulses that are intense …
extreme-ultraviolet to hard X-ray photons, providing ultrashort pulses that are intense …
Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks
J Zhang, L Liu, C Zheng, W Li, C Wang… - nature …, 2023 - nature.com
Spin-based sensors have attracted considerable attention owing to their high sensitivities.
Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption …
Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption …
Using X-ray free-electron lasers for spectroscopy of molecular catalysts and metalloenzymes
The metal centres in metalloenzymes and molecular catalysts are responsible for the
rearrangement of atoms and electrons during complex chemical reactions, and they enable …
rearrangement of atoms and electrons during complex chemical reactions, and they enable …
Chiral control of spin-crossover dynamics in Fe (II) complexes
Iron-based spin-crossover complexes hold tremendous promise as multifunctional switches
in molecular devices. However, real-world technological applications require the excited …
in molecular devices. However, real-world technological applications require the excited …
Progress in the theory of x-ray spectroscopy: From quantum chemistry to machine learning and ultrafast dynamics
CD Rankine, TJ Penfold - The Journal of Physical Chemistry A, 2021 - ACS Publications
The development of high-brilliance third-and fourth-generation light sources such as
synchrotrons and X-ray free-electron lasers (XFELs), the emergence of laboratory-based X …
synchrotrons and X-ray free-electron lasers (XFELs), the emergence of laboratory-based X …
Capturing photochemical and photophysical transformations in iron complexes with ultrafast X-ray spectroscopy and scattering
KJ Gaffney - Chemical Science, 2021 - pubs.rsc.org
Light-driven chemical transformations provide a compelling approach to understanding
chemical reactivity with the potential to use this understanding to advance solar energy and …
chemical reactivity with the potential to use this understanding to advance solar energy and …
Element-and enantiomer-selective visualization of molecular motion in real-time
Ultrafast optical-domain spectroscopies allow to monitor in real time the motion of nuclei in
molecules. Achieving element-selectivity had to await the advent of time resolved X-ray …
molecules. Achieving element-selectivity had to await the advent of time resolved X-ray …
Watching excited state dynamics with optical and X-ray probes: The excited state dynamics of aquocobalamin and hydroxocobalamin
RJ Sension, TP McClain, RM Lamb… - Journal of the …, 2023 - ACS Publications
Femtosecond time-resolved X-ray absorption (XANES) at the Co K-edge, X-ray emission
(XES) in the Co Kβ and valence-to-core regions, and broadband UV–vis transient …
(XES) in the Co Kβ and valence-to-core regions, and broadband UV–vis transient …
Observing the structural evolution in the photodissociation of diiodomethane with femtosecond solution X-ray scattering
Resolving the structural dynamics of the initial steps of chemical reactions is challenging.
We report the femtosecond time-resolved wide-angle x-ray scattering of the …
We report the femtosecond time-resolved wide-angle x-ray scattering of the …