Spin crossover nanomaterials: from fundamental concepts to devices
Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …
two electronic configurations with markedly different physical properties are excellent …
Spin crossover in discrete polynuclear iron (II) complexes
Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …
a wide variety of potential applications, including as displays, sensors, actuators or memory …
Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆
J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …
exchange and double exchange or spin crossover and valence tautomerism in small …
Thermal and Optical Switching of Iron(II) Complexes
P Gütlich, A Hauser, H Spiering - … Chemie International Edition …, 1994 - Wiley Online Library
The color change dark‐red⇌ colorless accompanies the transition of [Fe (l‐propyltetrazole)
6](BF4) 2 from the low‐spin state to the metastable high‐spin state. These states in this …
6](BF4) 2 from the low‐spin state to the metastable high‐spin state. These states in this …
Spin crossover—an overall perspective
P Gütlich, HA Goodwin - Spin Crossover in Transition Metal Compounds I, 2004 - Springer
In this chapter an outline is presented of the principal features of electronic spin crossover.
The development of the subject is traced and the various modes of manifestation of spin …
The development of the subject is traced and the various modes of manifestation of spin …
Communication between iron (II) building blocks in cooperative spin transition phenomena
JA Real, AB Gaspar, V Niel, MC Muñoz - Coordination Chemistry Reviews, 2003 - Elsevier
In the present article we discuss the cooperative nature of the spin crossover phenomenon
in iron (II) complexes, providing a perspective of the state of the art in this area. The first …
in iron (II) complexes, providing a perspective of the state of the art in this area. The first …
Thermal, pressure and light switchable spin-crossover materials
JA Real, AB Gaspar, MC Muñoz - Dalton Transactions, 2005 - pubs.rsc.org
This article reviews the most relevant chemical and structural aspects that influence the spin-
crossover phenomenon (SCO). Special attention is focussed on the recent development of …
crossover phenomenon (SCO). Special attention is focussed on the recent development of …
Spin crossover in a catenane supramolecular system
JA Real, E Andrés, MC Munoz, M Julve, T Granier… - Science, 1995 - science.org
The compound [Fe (tvp) 2 (NCS) 2]⋅ CH3OH, where tvp is 1, 2-di-(4-pyridyl)-ethylene, has
been synthesized and characterized by x-ray single-crystal diffraction. It consists of two …
been synthesized and characterized by x-ray single-crystal diffraction. It consists of two …
Understanding the origin of one-or two-step valence tautomeric transitions in bis (dioxolene)-bridged dinuclear cobalt complexes
Valence tautomerism (VT) involves a reversible stimulated intramolecular electron transfer
between a redox-active ligand and redox-active metal. Bis (dioxolene)-bridged dinuclear …
between a redox-active ligand and redox-active metal. Bis (dioxolene)-bridged dinuclear …
Multifunctionality in spin crossover materials
AB Gaspar, V Ksenofontov, M Seredyuk… - Coordination Chemistry …, 2005 - Elsevier
One of the most important trends in the spin crossover (SCO) field is focused on the
synthesis of new molecule-based functional materials in which the SCO properties may be …
synthesis of new molecule-based functional materials in which the SCO properties may be …