Understanding of cooperative effects in molecule-based spin transition materials

Y Fang, YS Meng, H Oshio, T Liu - Coordination Chemistry Reviews, 2024 - Elsevier
Spin transition (ST) materials, exhibiting spin state conversions by external stimuli, have
been studied for over a half-century and have been continuing research interests owing to …

Spin in Organic Cocrystals

C Zhang, X Wang, Y Li, Y Sun… - Chemistry–A European …, 2023 - Wiley Online Library
Organic spintronics has caused a huge revolution in creating highly efficient low‐power
circuits. Spin manipulation in organic cocrystals has become a promising strategy to uncover …

New aspects of vapochromic metal complexes: Cooperative phenomena in functions and structures

M Kato, M Yoshida, Y Sun, A Kobayashi - Journal of Photochemistry and …, 2022 - Elsevier
The latest trends in vapochromic materials that exhibit reversible color changes in response
to gas or vapor are reviewed. Since the end of the 20th century, studies on vapochromic …

Solvent Effects on the Structural and Magnetic Properties of FeIII Spin-Crossover Complexes

U Habarakada, T Boonprab, P Harding… - Crystal Growth & …, 2022 - ACS Publications
Molecular devices based on spin-crossover (SCO) compounds are important targets for
molecular electronics. In this study, six air-stable FeIII complexes have been prepared:[Fe …

ON/OFF Photo (switching) along with reversible spin-state change and single-crystal-to-single-crystal transformation in a mixed-valence Fe (II) Fe (III) molecular …

S Kamilya, S Mehta, M Semwal, R Lescouëzec… - Inorganic …, 2023 - ACS Publications
A mixed-valence Fe (II) Fe (III) molecular system,{[Fe (pzTp)(CN) 3] 2 [Fe (bik) 2] 2}·[Fe
(pzTp)(CN) 3] 2· 4MeOH (1· 4MeOH)(bik= bis-(1-methylimidazolyl)-2-methanone, pzTp …

Anion Modified Spin Crossover in [Fe(qsal-4-F)]+ Complexes with a 4-Position Substituted Qsal Ligand

HJ Sheng, CC Xia, XY Zhang, CC Zhang… - Inorganic …, 2022 - ACS Publications
Four iron (III) complexes,[Fe (qsal-4-F) 2] Y· sol (Hqsal-4-F= 4-fluoro-N-(8-quinolyl)
salicylaldimine; Y= NO3–, sol= 0.91 MeOH· 0.57 H2O (1NO3); Y= PF6–(2PF6); Y= BF4 …

Spin crossover crystalline materials engineered via single-crystal-to-single-crystal transformations

S Xue, Y Guo, Y Garcia - CrystEngComm, 2021 - pubs.rsc.org
Spin crossover continues to stimulate multidisciplinary research efforts worldwide as novel
potential applications of its intrinsic molecular bistability property are envisaged. The …

Improving spin crossover characteristics in heteroleptic [Fe III (qsal-5-I)(qsal-5-OMe)] A complexes

R Díaz-Torres, S Gómez-Coca, E Ruiz, P Harding… - Dalton …, 2023 - pubs.rsc.org
A family of heteroleptic spin crossover (SCO)[FeIII (qsal-5-I)(qsal-5-OMe)] A· sol (qsal-5-X= 5-
X-2-[(8-quinolylimino) methyl] phenolate; A= NO3− 1 sol= 2MeOH, NCS− 2 sol= 0.75 MeOH …

Co-crystallisation as a modular approach to the discovery of spin-crossover materials

LT Birchall, G Truccolo, L Jackson, HJ Shepherd - Chemical Science, 2022 - pubs.rsc.org
Herein we present co-crystallisation as a strategy for materials discovery in the field of
switchable spin crossover (SCO) systems. Using [Fe (3-bpp) 2]· 2A (where 3-bpp= 2, 6-bis …

35 Voices from Chemistry of Materials: Creativity, Collaboration, and Persistence

C Toro, SE Skrabalak - Chemistry of Materials, 2023 - ACS Publications
As part of the journal's 35th year celebration, we are collecting narratives from researchers
all over the world and sharing their experiences and aspirations. The first interviews …