Click-derived multifunctional metal complexes for diverse applications
The Click reaction that involves Cu (I)-catalyzed azide–alkyne cycloaddition (CuAAC) serves
as the most potent and highly dependable tool for the development of many complex …
as the most potent and highly dependable tool for the development of many complex …
Au⋅⋅⋅ H− C Interactions Support a Robust Thermally Activated Delayed Fluorescence (TADF) Gold (I) Complex for OLEDs with Little Efficiency Roll‐Off and Good …
X Feng, JG Yang, J Miao, C Zhong… - Angewandte Chemie …, 2022 - Wiley Online Library
The practical use of luminescent mononuclear gold (I) complexes as optoelectronic
materials has been limited by their inferior stability. Herein we demonstrate a strategy to …
materials has been limited by their inferior stability. Herein we demonstrate a strategy to …
Heart of gold: enabling ligands for oxidative addition of haloorganics in Au (i)/Au (iii) catalysed cross-coupling reactions
T McCallum - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
The field of Au-catalysis has been an area rich with new discoveries due to the unique
properties of the lustrous element. In the past decade, developments in Au (I)/Au (III) cross …
properties of the lustrous element. In the past decade, developments in Au (I)/Au (III) cross …
Au⋅⋅⋅ H− C Hydrogen Bonds as Design Principle in Gold (I) Catalysis
H Darmandeh, J Löffler, NV Tzouras… - Angewandte Chemie …, 2021 - Wiley Online Library
Secondary ligand–metal interactions are decisive in many catalytic transformations. While
arene–gold interactions have repeatedly been reported as critical structural feature in many …
arene–gold interactions have repeatedly been reported as critical structural feature in many …
Mechanochemical synthesis of (hetero) aryl Au (i) complexes
FJL Ingner, ZX Giustra, S Novosedlik, A Orthaber… - Green …, 2020 - pubs.rsc.org
Growing demand for sustainable chemical syntheses casts mechanochemistry in a new light
as an environmentally benign alternative to traditional solvent-based methods. Given recent …
as an environmentally benign alternative to traditional solvent-based methods. Given recent …
Deciphering the Primary Role of Au⋅⋅⋅ H− X Hydrogen Bonding in Gold Catalysis
A Sorroche, S Moreno, M Elena Olmos… - Angewandte …, 2023 - Wiley Online Library
Abstract Au⋅⋅⋅ H− X (X= N or C) hydrogen bonding is gaining increasing interest, both in
the study of its intrinsic nature and in their operability in different fields. While the role of …
the study of its intrinsic nature and in their operability in different fields. While the role of …
A topological data analysis perspective on noncovalent interactions in relativistic calculations
M Olejniczak… - International Journal of …, 2020 - Wiley Online Library
Abstract Topological Data Analysis (TDA) is a powerful mathematical theory, largely
unexplored in theoretical chemistry. In this work we demonstrate how TDA provides new …
unexplored in theoretical chemistry. In this work we demonstrate how TDA provides new …
Rare Au···H Interactions in Gold(I) Complexes of Bulky Phosphines Derived from 2,6-Dibenzhydryl-4-methylphenyl Core
MK Pandey, HS Kunchur, D Mondal… - Inorganic …, 2020 - ACS Publications
Gold (I) complexes of sterically demanding phosphines derived from 2, 6-dibenzhydryl-4-
methylphenyl core viz: 2, 6-dibenzhydryl-N, N-bis ((diphenylphosphane)-methyl)-4 …
methylphenyl core viz: 2, 6-dibenzhydryl-N, N-bis ((diphenylphosphane)-methyl)-4 …
A Rare Intramolecular Au···H–C(sp3) Interaction in a Gold(I) N-Heterocyclic Carbene
M Vaddamanu, A Sathyanarayana, Y Masaya… - …, 2020 - ACS Publications
We present a rare intramolecular Au··· H–C (sp 3) hydrogen-bonding interaction and
luminescent properties of a gold (I) carbene complex. The Au (I) complex [(L) Au (I) Cl](1) …
luminescent properties of a gold (I) carbene complex. The Au (I) complex [(L) Au (I) Cl](1) …
Reconstituting C-Centered Hexagold(I) Clusters with N-Heterocyclic Carbene Ligands
Ubiquitous intramolecular aurophilic interactions in gold clusters have usually been
assigned as the main determinants of their molecular geometry and various properties. By …
assigned as the main determinants of their molecular geometry and various properties. By …