Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

Asymmetric catalysis with transition‐metal complexes is the basis for a vast array of
stereoselective transformations and has changed the face of modern synthetic chemistry …

Interelement compounds, that is, compounds containing an interelement bond, 1 are
attractive main group element precursors as these provide the opportunity to transfer both …

An asymmetric Ni-catalyzed reductive cross-coupling has been developed to prepare
enantioenriched allylic silanes. This enantioselective reductive alkenylation proceeds under …

Organoboronic acids and their derivatives are useful reagents in carbon–carbon and carbon–
heteroatom bond formations. 1 In addition to having reasonable reactivities, organoboronic …

Chiral monophosphorus ligands are playing an important role for the recent advances in
asymmetric catalysis. This review summarizes the latest progress in various asymmetric …

A differentially protected diboron bearing the naphthalene-1, 8-diaminato group on one of
the two boron atoms undergoes highly regioselective diboration with terminal alkynes in the …

The present review is focused on the application of computational/theoretical methods to the
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …

New reactivities of silylboranes are described with their applications to organic synthesis.
The silylboranes add to unsaturated organic compounds such as alkynes, alkenes, 1, 3 …

A highly enantio‐and diastereoselective copper‐catalyzed three‐component coupling
affords the first general synthesis of homoallylic amines bearing adjacent stereocenters from …