Focusing on the recent literature (since 2000), this review outlines the main synthetic
approaches for the preparation of 5′-mono-, 5′-di-, and 5′-triphosphorylated …

Abstract 240 Years have passed since the discovery of elemental phosphorus. During that
time organophosphorus chemistry has emerged as an interesting and exciting field of …

Catalytic difunctionalization of alkenes has been an ideal strategy to generate structurally
complex molecules with diverse substitution patterns. Although both phosphonyl and …

Herein, we present a synthetic procedure for the facile and general preparation of novel S-
alkenyl and dienyl phosphoro (di) thioates for the first time. Extensive mechanistic …

Phosphorus fluoride exchange (PFEx) represents a cutting-edge advancement in catalytic
click-reaction technology. Drawing inspiration from nature's phosphate connectors, PFEx …

The first Ni-catalyzed C–O/P–H cross-coupling producing organophosphorus compounds is
disclosed. This method features wide generality in regard to both C–O and P–H compounds …

Organophosphine compounds are of high significance in organic synthesis, organometallic
chemistry, and materials science. The high demand for the incorporation of phosphine …

We carried out a comprehensive study on the generality, scope, limitations, and mechanism
of the palladium-catalyzed hydrophosphorylation of alkynes with P (O)–H compounds (ie, H …

A Pd-catalyzed dehydrogenative phosphorylation of thiols is developed. A variety of thiols
dehydrogenatively couple readily with all three kinds of P (O)–H compounds, ie, H …

An unprecedented electrochemically regioselective C–H phosphorothiolation and S-to C-[1,
4] phosphoryl migration involving indolizines, elemental sulfur, and H-phosphonates in an …