Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges
IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
Amide bond activation: the power of resonance
G Li, S Ma, M Szostak - Trends in Chemistry, 2020 - cell.com
The amide bond represents the most fundamental functional group in numerous areas of
chemistry, such as organic synthesis, drug discovery, polymers, and biochemistry. Although …
chemistry, such as organic synthesis, drug discovery, polymers, and biochemistry. Although …
Transition-metal mediated carbon–sulfur bond activation and transformations: an update
J Lou, Q Wang, P Wu, H Wang, YG Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …
Amide activation: an emerging tool for chemoselective synthesis
D Kaiser, A Bauer, M Lemmerer… - Chemical Society Reviews, 2018 - pubs.rsc.org
It is textbook knowledge that carboxamides benefit from increased stabilisation of the
electrophilic carbonyl carbon when compared to other carbonyl and carboxyl derivatives …
electrophilic carbonyl carbon when compared to other carbonyl and carboxyl derivatives …
Selective decarbonylation via transition-metal-catalyzed carbon–carbon bond cleavage
H Lu, TY Yu, PF Xu, H Wei - Chemical Reviews, 2020 - ACS Publications
Transition-metal-catalyzed decarbonylation via carbon–carbon bond cleavage is an
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …
Cross-coupling of amides by N–C bond activation
G Meng, S Shi, M Szostak - Synlett, 2016 - thieme-connect.com
In recent years, significant conceptual advances have taken place in the field of amide bond
cross-coupling. Mild and selective functionalization of amides by transition-metal catalysis …
cross-coupling. Mild and selective functionalization of amides by transition-metal catalysis …
Decarbonylative cross-couplings: nickel catalyzed functional group interconversion strategies for the construction of complex organic molecules
L Guo, M Rueping - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The utilization of carboxylic acid esters as electrophiles in metal-catalyzed cross-
coupling reactions is increasingly popular, as environmentally friendly and readily available …
coupling reactions is increasingly popular, as environmentally friendly and readily available …
Decarbonylative cross-coupling of amides
C Liu, M Szostak - Organic & Biomolecular Chemistry, 2018 - pubs.rsc.org
Cross-coupling reactions are among the most powerful C–C and C–X bond forming tools in
organic chemistry. Traditionally, cross-coupling methods rely on the use of aryl halides or …
organic chemistry. Traditionally, cross-coupling methods rely on the use of aryl halides or …
Recent advances in the metal‐catalyzed activation of amide bonds
MB Chaudhari… - Chemistry–An Asian …, 2019 - Wiley Online Library
The amide functional group is commonly found in peptides, proteins, pharmaceutical
compounds, natural products, and polymers. The synthesis of amides is typically performed …
compounds, natural products, and polymers. The synthesis of amides is typically performed …
Ni-catalyzed aryl sulfide synthesis through an aryl exchange reaction
R Isshiki, MB Kurosawa, K Muto… - Journal of the American …, 2021 - ACS Publications
A Ni-catalyzed aryl sulfide synthesis through an aryl exchange reaction between aryl
sulfides and a variety of aryl electrophiles was developed. By using 2-pyridyl sulfide as a …
sulfides and a variety of aryl electrophiles was developed. By using 2-pyridyl sulfide as a …