Reactions of hydrosilanes with transition metal complexes

JY Corey - Chemical Reviews, 2016 - ACS Publications
This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis

FJ Fernández-Alvarez, R Lalrempuia, LA Oro - Coordination Chemistry …, 2017 - Elsevier
The number of late transition metal complexes bearing tridentate monoanionic silyl-based
NSiN-type ligands has grown in the last few years. This review describes the synthetic …

Carbon–hydrogen versus nitrogen–oxygen bond activation in reactions of N-oxide derivatives of 2, 2′-bipyridine and 1, 10-phenanthroline with a dimethylplatinum (II …

ME Moustafa, PD Boyle, RJ Puddephatt - Organometallics, 2014 - ACS Publications
The reactions of the potential oxygen atom donor ligands 1, 10-phenanthroline N-oxide
(phenO) and 2, 2′-bipyridine N-oxide (bipyO) with the dimethylplatinum (II) complex …

Phosphorescent Ir (III) complexes with both cyclometalate chromophores and phosphine-silanolate ancillary: concurrent conversion of organosilane to silanolate

F Zhang, L Wang, SH Chang, KL Huang, Y Chi… - Dalton …, 2013 - pubs.rsc.org
Ir (III) metal complexes with general formula [(C^ N) 2Ir (P^ SiO)], where (C^ N) H is 2-
phenylisoquinoline (1), 2-phenylpyridine (2) or 2-(2, 4-difluorophenyl) pyridine (3), and (P …

Hydrolysis of organometallic and metal–amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide …

JA Garden, SD Pike - Dalton Transactions, 2018 - pubs.rsc.org
The hydrolysis reaction between Brønsted basic organometallic or metal–amide reagents
with Brønsted acidic OH groups from water or metal–hydroxides may act as a controlled …

Si–C bond cleavage by hydride complexes of rhodium and iridium: comparison of Si–C (sp 2) and Si–C (sp 3) activation

H Kameo, S Ishii, H Nakazawa - Dalton Transactions, 2013 - pubs.rsc.org
Single Si–CR (R= Ph, Me, Et) bond activation in {o-(Ph2P) C6H4} 2Si (Me)(R) induced by
Rh (H)(CO)(PPh3) 3 was developed. The efficiency of Si–CR bond breaking reactions …

Supramolecular organometallic chemistry: the platinum (iv) paradigm

RJ Puddephatt - Dalton Transactions, 2022 - pubs.rsc.org
Supramolecular chemistry and the chemistry of alkyl derivatives of the transition metals are
both topics of considerable current interest, but the combination of the two fields is still …

Facial–Meridional Isomerization and Reductive Elimination in [(R2P-o-C6H4)2N]PtMe3 (R = Ph, iPr)

LC Liang, SM Liao, XR Zou - Inorganic Chemistry, 2021 - ACS Publications
Treatment of PtMe3I in tetrahydrofuran with either in situ prepared [R-PNP] Li ([R-
PNP]−=[(R2P-o-C6H4) 2N]−; R= Ph, i Pr) or H [R-PNP] in the presence of triethylamine at …

Activation of Molecular Hydrogen and Oxygen by PSiP Complexes of Cobalt

LJ Murphy, AJ Ruddy, R McDonald… - European Journal of …, 2018 - Wiley Online Library
The syntheses of CoII halide complexes supported by κ3‐(2‐Cy2PC6H4) 2SiMe (Cy‐PSiP)
ligation are detailed. Reduction of (Cy‐PSiP) Co (PMe3) I could be achieved under mild …

Reactivity of organoplatinum complexes containing appended alcohol functional groups: Activation of dioxygen and hydrogen peroxide

KA Thompson, C Kadwell, PD Boyle… - Journal of Organometallic …, 2017 - Elsevier
The oxidative addition reactions of platinum (II) complexes [PtMe 2 (RN= CH-2-C 5 H 4 N)],
especially when R= CH 2 CH 2 OH or CH 2 CH 2 CH 2 OH, have been studied. Both …