Platinum-catalyzed hydrosilylation in polymer chemistry

RY Lukin, AM Kuchkaev, AV Sukhov… - Polymers, 2020 - mdpi.com
This paper addresses a review of platinum-based hydrosilylation catalysts. The main field of
application of these catalysts is the curing of silicone polymers. Since the 1960s, this area …

Metal carbonyl clusters of groups 8–10: synthesis and catalysis

C Cesari, JH Shon, S Zacchini… - Chemical Society Reviews, 2021 - pubs.rsc.org
In this review article, we discuss advances in the chemistry of metal carbonyl clusters
(MCCs) spanning the last three decades, with an emphasis on the more recent reports and …

Catalysis of hydrosilylation of carbon-carbon multiple bonds: Recent progress

B Marciniec - Silicon Chemistry, 2002 - Springer
Recent progress in the catalytic hydrosilylation of organic and organosilicon compounds
containing carbon-carbon multiple bonds is reviewed. Related to this, dehydrogenative …

Functionalized polysilalkylene siloxanes (polycarbosiloxanes) by hydrosilylation—Catalysis and synthesis

S Putzien, O Nuyken, FE Kühn - Progress in Polymer Science, 2010 - Elsevier
Polysilalkylene siloxanes or 'hybrid silicones' are a comparatively new class of polymeric
materials combining the chemical properties of silicones and paraffins in a unique way. They …

Ruthenium-catalysed hydrosilylation of carbon–carbon multiple bonds

M Zaranek, B Marciniec, P Pawluć - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Ruthenium-based complexes are generally considered to be efficient catalysts due to their
high activity and electron transfer features. Although there are a limited number of highly …

Photocatalyzed hydrosilylation in silicone chemistry

AV Radchenko, F Ganachaud - Industrial & Engineering …, 2022 - ACS Publications
Hydrosilylation is widely used in silicone chemistry to cross-link formulations so as to
generate elastomer materials. Most often, heat is the easiest way to activate a platinum …

Recent advances in the hydrosilylation and related reactions

I Ojima, Z Li, J Zhu - The chemistry of organic silicon …, 1998 - Wiley Online Library
Hydrosilylation, especially of carbon carbon multiple bonds, is one of the most important
reactions in organosilicon chemistry, and thus the reaction has been studied extensively for …

Successive C–C coupling of dienes to vicinally dioxygenated hydrocarbons: ruthenium catalyzed [4+ 2] cycloaddition across the diol, hydroxycarbonyl, or dione …

LM Geary, BW Glasspoole, MM Kim… - Journal of the American …, 2013 - ACS Publications
The ruthenium (0) catalyst generated from Ru3 (CO) 12 and tricyclohexylphosphine or
BIPHEP promotes successive C–C coupling of dienes to vicinally dioxygenated …

Hydrosilylation and related reactions of silicon compounds

B Marciniec, H Maciejewski… - … Handbook in Four …, 2017 - Wiley Online Library
This chapter presents the hydrosilylation processes and gives a brief account of the main
types of reactions related to hydrosilylation in which the intermediates with a metal‐silicon …

Partially charged single-atom Ru supported on ZrO2 nanocrystals for highly efficient ethylene hydrosilylation with triethoxysilane

M Li, S Zhao, J Li, X Chen, Y Ji, H Yu, D Bai, G Xu… - Nano Research, 2022 - Springer
Homogeneous noble metal catalysts used in alkene hydrosilylation reactions to manufacture
organosilicon compounds commercially often suffer from difficulties in catalyst recovering …