Palladium-catalyzed transformations of alkyl C–H bonds

J He, M Wasa, KSL Chan, Q Shao, JQ Yu - Chemical Reviews, 2017 - ACS Publications
This Review summarizes the advancements in Pd-catalyzed C (sp3)–H activation via
various redox manifolds, including Pd (0)/Pd (II), Pd (II)/Pd (IV), and Pd (II)/Pd (0). While few …

Conducting polymers for optoelectronic devices and organic solar cells: A review

A R. Murad, A Iraqi, SB Aziz, S N. Abdullah, MA Brza - Polymers, 2020 - mdpi.com
In this review paper, we present a comprehensive summary of the different organic solar cell
(OSC) families. Pure and doped conjugated polymers are described. The band structure …

Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Solvent effects in palladium catalysed cross-coupling reactions

J Sherwood, JH Clark, IJS Fairlamb, JM Slattery - Green Chemistry, 2019 - pubs.rsc.org
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Direct (hetero) arylation polymerization: simplicity for conjugated polymer synthesis

JR Pouliot, F Grenier, JT Blaskovits, S Beaupré… - Chemical …, 2016 - ACS Publications
Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Transition-metal-free coupling reactions

CL Sun, ZJ Shi - Chemical reviews, 2014 - ACS Publications
Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview of commonly employed DFT methods …

T Sperger, IA Sanhueza, I Kalvet… - Chemical …, 2015 - ACS Publications
The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Palladium catalyzed C–C and C–N bond forming reactions: an update on the synthesis of pharmaceuticals from 2015–2020

J Rayadurgam, S Sana, M Sasikumar… - Organic Chemistry …, 2021 - pubs.rsc.org
Some of the most prominent and promising catalysts in organic synthesis for the requisite
construction of C–C and C–N bonds are palladium (Pd) catalysts, which play a pivotal role in …

Site-selective cross-coupling of polyhalogenated arenes and heteroarenes with identical halogen groups

V Palani, MA Perea, R Sarpong - Chemical reviews, 2021 - ACS Publications
Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …

The Stille reaction, 38 years later

C Cordovilla, C Bartolomé, JM Martinez-Ilarduya… - Acs …, 2015 - ACS Publications
The first now-named Stille reaction was published 38 years ago, and the last comprehensive
revision of this catalysis was in 2004. Since then, the knowledge of the different steps of the …