Shaping the structure and response of surface-grafted polymer brushes via the molecular weight distribution

JC Conrad, ML Robertson - JACS Au, 2023 - ACS Publications
Breadth in the molecular weight distribution is an inherent feature of synthetic polymer
systems. While in the past this was typically considered as an unavoidable consequence of …

Non-universal features in uniaxially extensional rheology of linear polymer melts and concentrated solutions: A review

Y Matsumiya, H Watanabe - Progress in Polymer Science, 2021 - Elsevier
Rheological behavior of polymeric liquids has been considered to be universally determined
by a few time-independent molecular parameters (such as the Rouse relaxation time and …

Melt blown nanofibers: Fiber diameter distributions and onset of fiber breakup

CJ Ellison, A Phatak, DW Giles, CW Macosko, FS Bates - Polymer, 2007 - Elsevier
Poly (butylene terephthalate), polypropylene, and polystyrene nanofibers with average
diameters less than 500nm have been produced by a single orifice melt blowing apparatus …

When polymer chains are highly aligned: a perspective on extensional rheology

Q Huang - Macromolecules, 2022 - ACS Publications
We provide a Perspective on recent findings in extensional rheology for polymer melts and
solutions with different macromolecular architectures. For linear polymer systems, we focus …

Concentrated polymer solutions are different from melts: Role of entanglement molecular weight

Q Huang, O Mednova, HK Rasmussen… - …, 2013 - ACS Publications
We compare viscoelastic properties of several polystyrene solutions and melts with the
same number of entanglements. It is demonstrated that the modulus and time can be shifted …

Unexpected stretching of entangled ring macromolecules

Q Huang, J Ahn, D Parisi, T Chang, O Hassager… - Physical review …, 2019 - APS
In the melt state at equilibrium, entangled nonconcatenated ring macromolecules adapt
more compact conformations compared to their linear analogs and do not form an …

Primitive chain network simulation of elongational flows of entangled linear chains: Stretch/orientation-induced reduction of monomeric friction

T Yaoita, T Isaki, Y Masubuchi, H Watanabe… - …, 2012 - ACS Publications
Well-entangled monodisperse linear polystyrene melts exhibit monotonic thinning of the
steady state elongational viscosity with increasing the strain rate ε̇ even beyond the Rouse …

Modeling the rheology of polymer melts and solutions

RG Larson, PS Desai - Annual Review of Fluid Mechanics, 2015 - annualreviews.org
We review constitutive modeling of solutions and melts of linear polymers, focusing on
changes in rheological behavior in shear and extensional flow as the concentration …

The rheology of aqueous solutions of ethyl hydroxy-ethyl cellulose (EHEC) and its hydrophobically modified analogue (hmEHEC): extensional flow response in …

V Sharma, SJ Haward, J Serdy, B Keshavarz… - Soft matter, 2015 - pubs.rsc.org
Cellulose derivatives containing associating hydrophobic groups along their hydrophilic
backbone are used as rheology modifiers in the formulation of water-based spray paints …

Relating chain conformations to extensional stress in entangled polymer melts

TC O'Connor, NJ Alvarez, MO Robbins - Physical review letters, 2018 - APS
Nonlinear extensional flows are common in polymer processing, but they remain
challenging theoretically because dramatic stretching of chains deforms the entanglement …