Shaping the structure and response of surface-grafted polymer brushes via the molecular weight distribution
JC Conrad, ML Robertson - JACS Au, 2023 - ACS Publications
Breadth in the molecular weight distribution is an inherent feature of synthetic polymer
systems. While in the past this was typically considered as an unavoidable consequence of …
systems. While in the past this was typically considered as an unavoidable consequence of …
Non-universal features in uniaxially extensional rheology of linear polymer melts and concentrated solutions: A review
Y Matsumiya, H Watanabe - Progress in Polymer Science, 2021 - Elsevier
Rheological behavior of polymeric liquids has been considered to be universally determined
by a few time-independent molecular parameters (such as the Rouse relaxation time and …
by a few time-independent molecular parameters (such as the Rouse relaxation time and …
Melt blown nanofibers: Fiber diameter distributions and onset of fiber breakup
Poly (butylene terephthalate), polypropylene, and polystyrene nanofibers with average
diameters less than 500nm have been produced by a single orifice melt blowing apparatus …
diameters less than 500nm have been produced by a single orifice melt blowing apparatus …
When polymer chains are highly aligned: a perspective on extensional rheology
Q Huang - Macromolecules, 2022 - ACS Publications
We provide a Perspective on recent findings in extensional rheology for polymer melts and
solutions with different macromolecular architectures. For linear polymer systems, we focus …
solutions with different macromolecular architectures. For linear polymer systems, we focus …
Concentrated polymer solutions are different from melts: Role of entanglement molecular weight
Q Huang, O Mednova, HK Rasmussen… - …, 2013 - ACS Publications
We compare viscoelastic properties of several polystyrene solutions and melts with the
same number of entanglements. It is demonstrated that the modulus and time can be shifted …
same number of entanglements. It is demonstrated that the modulus and time can be shifted …
Unexpected stretching of entangled ring macromolecules
In the melt state at equilibrium, entangled nonconcatenated ring macromolecules adapt
more compact conformations compared to their linear analogs and do not form an …
more compact conformations compared to their linear analogs and do not form an …
Primitive chain network simulation of elongational flows of entangled linear chains: Stretch/orientation-induced reduction of monomeric friction
T Yaoita, T Isaki, Y Masubuchi, H Watanabe… - …, 2012 - ACS Publications
Well-entangled monodisperse linear polystyrene melts exhibit monotonic thinning of the
steady state elongational viscosity with increasing the strain rate ε̇ even beyond the Rouse …
steady state elongational viscosity with increasing the strain rate ε̇ even beyond the Rouse …
Modeling the rheology of polymer melts and solutions
We review constitutive modeling of solutions and melts of linear polymers, focusing on
changes in rheological behavior in shear and extensional flow as the concentration …
changes in rheological behavior in shear and extensional flow as the concentration …
The rheology of aqueous solutions of ethyl hydroxy-ethyl cellulose (EHEC) and its hydrophobically modified analogue (hmEHEC): extensional flow response in …
Cellulose derivatives containing associating hydrophobic groups along their hydrophilic
backbone are used as rheology modifiers in the formulation of water-based spray paints …
backbone are used as rheology modifiers in the formulation of water-based spray paints …
Relating chain conformations to extensional stress in entangled polymer melts
Nonlinear extensional flows are common in polymer processing, but they remain
challenging theoretically because dramatic stretching of chains deforms the entanglement …
challenging theoretically because dramatic stretching of chains deforms the entanglement …