Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians

C Rudowicz, M Karbowiak - Coordination Chemistry Reviews, 2015 - Elsevier
This review provides a summary of distinct Hamiltonians used to describe magnetic and
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …

The Use of Magnetic Dilution To Elucidate the Slow Magnetic Relaxation Effects of a Dy2 Single-Molecule Magnet

F Habib, PH Lin, J Long, I Korobkov… - Journal of the …, 2011 - ACS Publications
The magnetic dilution method was employed in order to elucidate the origin of the slow
relaxation of the magnetization in a Dy2 single-molecule magnet (SMM). The doping effect …

Application of Hard and Soft Acid‐base Theory to Construct Heterometallic Materials with Metal‐oxo Clusters

X Qi, YL Xie, JY Niu, JW Zhao, YM Li… - Angewandte Chemie …, 2025 - Wiley Online Library
Heterometallic cluster‐based materials offer the potential to incorporate multiple
functionalities, leveraging the aggregation effects of clusters and translating this …

Cyanide single-molecule magnets exhibiting solvent dependent reversible “on” and “off” exchange bias behavior

D Pinkowicz, HI Southerland, C Avendaño… - Journal of the …, 2015 - ACS Publications
The syntheses, structures, and magnetic properties of four new complex salts,(PPN){[MnIII
(salphen)(MeOH)] 2 [MIII (CN) 6]}· 7MeOH (Mn2M· 7MeOH)(M= Fe, Ru, Os and Co; PPN+ …

What controls the sign and magnitude of magnetic anisotropy in tetrahedral cobalt (II) single-ion magnets?

S Vaidya, S Tewary, SK Singh, SK Langley… - Inorganic …, 2016 - ACS Publications
A family of mononuclear tetrahedral cobalt (II) thiourea complexes,[Co (L1) 4](NO3) 2 (1)
and [Co (L x) 4](ClO4) 2 where x= 2 (2), 3 (3), 4 (4)(where L1= thiourea, L2= 1, 3 …

Slow Magnetic Relaxation Induced by a Large Transverse Zero-Field Splitting in a MnIIReIV(CN)2 Single-Chain Magnet

X Feng, J Liu, TD Harris, S Hill… - Journal of the American …, 2012 - ACS Publications
The model compounds (NBu4) 2 [ReCl4 (CN) 2](1),(DMF) 4ZnReCl4 (CN) 2 (2), and
[(PY5Me2) 2Mn2ReCl4 (CN) 2](PF6) 2 (3) have been synthesized to probe the origin of the …

Triimidosulfonates as Acute Bite‐Angle Chelates: Slow Relaxation of the Magnetization in Zero Field and Hysteresis Loop of a CoII Complex

E Carl, S Demeshko, F Meyer… - Chemistry–A European …, 2015 - Wiley Online Library
Starting from a polyimido sulfonate the four‐coordinate, N, N′‐chelated CoII complex [Co
{(NtBu) 3SMe} 2](1) was synthesized, and its molecular structure was elucidated by single …

A supramolecular aggregate of four exchange-biased single-molecule magnets

TN Nguyen, W Wernsdorfer, KA Abboud… - Journal of the …, 2011 - ACS Publications
The reaction between 3-phenyl-1, 5-bis (pyridin-2-yl) pentane-1, 5-dione dioxime (pdpdH2)
and triangular [MnIII3O (O2CMe)(py) 3](ClO4)(1) affords [Mn12O4 (O2CMe) 12 (pdpd) …

Reversible Solvatomagnetic Effect in Novel Tetranuclear Cubane-Type Ni4 Complexes and Magnetostructural Correlations for the [Ni43-O)4] Core

A Das, FJ Klinke, S Demeshko, S Meyer… - Inorganic …, 2012 - ACS Publications
A new family of tetranuclear nickel cube complexes [Ni4L4 (solv) 4](1, solv= MeOH; 2, solv=
H2O; H2L= pyrazole-based tridentate {ONO} ligand) has been studied in detail, in particular …

Single-benzene solid emitters with lasing properties based on aggregation-induced emissions

B Tang, H Liu, F Li, Y Wang, H Zhang - Chemical Communications, 2016 - pubs.rsc.org
The very simple organic molecules have been employed to construct highly efficient single-
benzene solid emitters (quantum yields: 0.72–0.84) with crystal lasing properties based on …