Mixed-metal metal–organic frameworks
S Abednatanzi, PG Derakhshandeh… - Chemical Society …, 2019 - pubs.rsc.org
Mixed-metal MOFs are metal–organic frameworks that contain at least 2 different metal ions
as nodes of their frameworks. They are prepared relatively easily by either a one-pot …
as nodes of their frameworks. They are prepared relatively easily by either a one-pot …
Solid-state NMR investigations of carbon dioxide gas in metal–organic frameworks: insights into molecular motion and adsorptive behavior
Solid-state nuclear magnetic resonance (SSNMR) methods have been routinely used for the
characterization of both the structure and the dynamics of metal organic frameworks (MOFs) …
characterization of both the structure and the dynamics of metal organic frameworks (MOFs) …
Combining In Situ Techniques (XRD, IR, and 13C NMR) and Gas Adsorption Measurements Reveals CO2-Induced Structural Transitions and High CO2/CH4 …
Flexible metal–organic frameworks (MOFs) are promising materials in gas-related
technologies. Adjusting the material to processes requires understanding of the flexibility …
technologies. Adjusting the material to processes requires understanding of the flexibility …
Probing molecular motions in metal-organic frameworks with solid-state NMR
Molecular motions in metal-organic frameworks (MOFs) are important phenomena that
involve the sorption of gases, the rotation of linkers, the diffusion of ions, the reaction of …
involve the sorption of gases, the rotation of linkers, the diffusion of ions, the reaction of …
Exploiting NMR spectroscopy for the study of disorder in solids
RF Moran, DM Dawson… - International Reviews in …, 2017 - Taylor & Francis
Although the solid state is typically characterised by inherent periodicity, many interesting
physical and chemical properties of solids arise from a variation in this, ie changes in the …
physical and chemical properties of solids arise from a variation in this, ie changes in the …
Solid‐State NMR Spectroscopy: A Powerful Technique to Directly Study Small Gas Molecules Adsorbed in Metal–Organic Frameworks
Metal–organic frameworks (MOFs) have shown great potential in gas separation and
storage, and the design of MOFs for these purposes is an on‐going field of research. Solid …
storage, and the design of MOFs for these purposes is an on‐going field of research. Solid …
Cold, Hot, Dry, and Wet: Locations and Dynamics of CO2 and H2O Co-Adsorbed in an Ultramicroporous MOF
V Martins, BEG Lucier, Z Liu, H Liang, A Zheng… - Inorganic …, 2023 - ACS Publications
Climate change from anthropogenic carbon dioxide (CO2) emissions poses a severe threat
to society. A variety of mitigation strategies currently include some form of CO2 capture …
to society. A variety of mitigation strategies currently include some form of CO2 capture …
In Situ 13C NMR Spectroscopy Study of CO2/CH4 Mixture Adsorption by Metal–Organic Frameworks: Does Flexibility Influence Selectivity?
M Sin, N Kavoosi, M Rauche, J Pallmann, S Paasch… - Langmuir, 2019 - ACS Publications
Metal–organic frameworks are promising candidates for selective separation processes
such as CO2 removal from methane (natural gas sweetening). Framework flexibility, that is …
such as CO2 removal from methane (natural gas sweetening). Framework flexibility, that is …
The Surprising Stability of Cu3(btc)2 Metal–Organic Framework under Steam Flow at High Temperature
It is widely admitted that metal–organic frameworks (MOFs) are water sensitive and that high
temperatures accelerate the hydrolysis phenomena and the collapse of the porous network …
temperatures accelerate the hydrolysis phenomena and the collapse of the porous network …
“Hidden” CO2 in Amine-Modified Porous Silicas Enables Full Quantitative NMR Identification of Physi- and Chemisorbed CO2 Species
Although spectroscopic investigation of surface chemisorbed CO2 species has been the
focus of most studies, identifying different domains of weakly interacting (physisorbed) CO2 …
focus of most studies, identifying different domains of weakly interacting (physisorbed) CO2 …