Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure− activity relationships
EYX Chen, TJ Marks - Chemical Reviews, 2000 - ACS Publications
One of the most exciting developments in the areas of catalysis, organometallic chemistry,
and polymer science in recent years has been the intense exploration and …
and polymer science in recent years has been the intense exploration and …
The search for new‐generation olefin polymerization catalysts: life beyond metallocenes
GJP Britovsek, VC Gibson… - Angewandte Chemie …, 1999 - Wiley Online Library
Even late transition metal complexes function as active and selective catalysts for α‐olefin
polymerization. The discovery of a highly active family of catalysts 1 based on iron, a metal …
polymerization. The discovery of a highly active family of catalysts 1 based on iron, a metal …
The search for larger and more weakly coordinating anions
SH Strauss - Chemical Reviews, 1993 - ACS Publications
It has been 20 years since Rosenthal published his brief paper titled “The Myth of the Non-
Coordinating Anion”. 1 In this seminal work, he reviewed structural and spectroscopic data …
Coordinating Anion”. 1 In this seminal work, he reviewed structural and spectroscopic data …
Auf der Suche nach einer neuen Generation von Katalysatoren zur Olefinpolymerisation:„Leben” ︁ jenseits der Metallocene
GJP Britovsek, VC Gibson, DF Wass - Angewandte Chemie, 1999 - Wiley Online Library
Auch Komplexe später Übergangsmetalle sind aktive und selektive Katalysatoren für die
Polymerisation von α‐Olefinen. Die Entdeckung einer Klasse hochaktiver …
Polymerisation von α‐Olefinen. Die Entdeckung einer Klasse hochaktiver …
Reactivity of metallocene catalysts for olefin polymerization: influence of activator nature and structure
JN Pédeutour, K Radhakrishnan… - Macromolecular …, 2001 - Wiley Online Library
In this review, various synthetic and structural aspects of methylaluminoxane and the
elementary processes involved in olefin polymerization, as identified by various …
elementary processes involved in olefin polymerization, as identified by various …
Synthesis of syndiotactic polystyrene: reaction mechanisms and catalysis
R Pó, N Cardi - Progress in polymer science, 1996 - Elsevier
In this review the scientific and patent literature on the synthesis of syndiotactic poly
(styrene)(SPS) is discussed. SPS can be obtained using titanium compounds …
(styrene)(SPS) is discussed. SPS can be obtained using titanium compounds …
Ethylene, styrene, and α-methylstyrene polymerization by mono (pentamethylcyclopentadienyl)(Cp*) complexes of titanium, zirconium, and hafnium: roles of cationic …
Q Wang, R Quyoum, DJ Gillis, MJ Tudoret… - …, 1996 - ACS Publications
A variety of monocyclopentadienyl and mono (pentamethylcyclopentadienyl) complexes of
titanium, zirconium, and hafnium are assessed for abilities to initiate polymerization of …
titanium, zirconium, and hafnium are assessed for abilities to initiate polymerization of …
Influence of metallocene structures on ethene copolymerization with 1-butene and 1-octene
J Suhm, MJ Schneider, R Mülhaupt - Journal of Molecular Catalysis A …, 1998 - Elsevier
Ethene/1-octene and ethene/1-butene copolymerization using various methylaluminoxane-
activated metallocene catalysts, eg silylene-bridged substituted bisindenyl zirconocene …
activated metallocene catalysts, eg silylene-bridged substituted bisindenyl zirconocene …
New catalyst of SO 4 2− /Al2O3–ZrO2 for n-butane isomerization
Z Gao, Y Xia, W Hua, C Miao - Topics in Catalysis, 1998 - Springer
The catalytic behavior of Al-promoted sulfated zirconia for n-butane isomerization at low
temperature in the absence of H 2 and at high temperature in the presence of H 2 was …
temperature in the absence of H 2 and at high temperature in the presence of H 2 was …
Alternating ethylene− styrene copolymerization with a methylaluminoxane-free half-titanocene catalyst
C Pellecchia, D Pappalardo, M D'Arc… - Macromolecules, 1996 - ACS Publications
Copolymerization of ethylene and styrene in the presence of the catalytic system η5-
C5Me5Ti (CH2Ph) 3− B (C6F5) 3 has been investigated. Independently from the feed …
C5Me5Ti (CH2Ph) 3− B (C6F5) 3 has been investigated. Independently from the feed …