Infrared spectroscopy of helium nanodroplets: novel methods for physics and chemistry

MY Choi, GE Douberly, TM Falconer… - … Reviews in Physical …, 2006 - Taylor & Francis
Helium nanodroplets have emerged as a new and exciting medium for studying the structure
and dynamics of both this quantum solvent and impurities that can be doped into (onto) and …

The chemistry of disks around T Tauri and Herbig Ae/Be stars

M Agúndez, E Roueff, F Le Petit… - Astronomy & Astrophysics, 2018 - aanda.org
Context. Infrared and (sub-) millimeter observations of disks around T Tauri and Herbig
Ae/Be stars point to a chemical differentiation, with a lower detection rate of molecules in …

Molecular beam studies of free-radical processes: photodissociation, inelastic and reactive collisions

JC Whitehead - Reports on Progress in Physics, 1996 - iopscience.iop.org
In this review, the production and detection of a wide range of unstable free-radical species
under molecular beam conditions are described. The use of such molecular beam methods …

Chemical reactions in quantum crystals

T Momose, M Fushitani §… - International Reviews in …, 2005 - Taylor & Francis
Solid parahydrogen, known as a quantum crystal, is a novel matrix for the study of physical
and chemical processes of molecules at low temperatures by high-resolution infrared …

An ab initio study of the ground and excited electronic states of the methyl radical

A Zanchet, L Bañares, ML Senent… - Physical Chemistry …, 2016 - pubs.rsc.org
The ground and some excited electronic states of the methyl radical have been
characterized by means of highly correlated ab intio techniques. The specific excited states …

Direct measurement of methyl radicals in a methane/air flame at atmospheric pressure by radar REMPI

Y Wu, A Bottom, Z Zhang, TM Ombrello, VR Katta - Optics express, 2011 - opg.optica.org
We report the direct measurements of methyl radicals (CH_3) in methane/air flames at
atmospheric pressure by using coherent microwave Rayleigh scattering (Radar) from …

New theoretical infrared line list for the methyl radical with accurate vibrational band origins from high-level ab initio calculations

O Egorov, M Rey, AV Nikitin… - The Journal of Physical …, 2022 - ACS Publications
In the present work, high-level ab initio calculations were carried out for the ground
electronic state of the methyl radical (CH3). Dunning's augmented correlation-consistent …

Infrared laser spectroscopy of CH3⋯ HF in helium nanodroplets: The exit-channel complex of the F+ CH4 reaction

JM Merritt, S Rudić, RE Miller - The Journal of chemical physics, 2006 - pubs.aip.org
High-resolution infrared laser spectroscopy is used to study the CH 3⋯ HF and CD 3⋯ HF
radical complexes, corresponding to the exit-channel complex in the F+ CH 4→ H F+ CH 3 …

Imaging the photodissociation dynamics of the methyl radical from the 3s and 3p z Rydberg states

SM Poullain, DV Chicharro, A Zanchet… - Physical Chemistry …, 2016 - pubs.rsc.org
The photodissociation dynamics of the methyl radical from the 3s and 3pz Rydberg states
have been studied using the velocity map and slice ion imaging in combination with pump …

Analysis of 205-nm photolytic production of atomic hydrogen in methane flames

WD Kulatilaka, JH Frank, BD Patterson, TB Settersten - Applied Physics B, 2009 - Springer
We investigate the 205-nm photolytic production of atomic hydrogen in methane flames. This
process represents a significant interference in two-photon, laser induced-fluorescence (TP …