Chemistry of Carbon-Substituted Derivatives of Cobalt Bis(dicarbollide)(1) Ion and Recent Progress in Boron Substitution

L Pazderová, EZ Tüzün, D Bavol, M Litecká, L Fojt… - Molecules, 2023 - mdpi.com
The cobalt bis (dicarbollide)(1−) anion (1−),[(1, 2-C2B9H11) 2-3, 3′-Co (III)](1−), plays an
increasingly important role in material science and medicine due to its high chemical …

Enzyme Immobilization using Covalent Organic Frameworks: From Synthetic Strategy to COFs Functional Role

X Fan, S Zhai, S Xue, L Zhi - ACS Applied Materials & Interfaces, 2024 - ACS Publications
Enzymes, a class of biocatalysts, exhibit remarkable catalytic efficiency, specificity, and
selectivity, governing many reactions that are essential for various cascades within living …

Elucidation of the role of metals in the adsorption and photodegradation of herbicides by metal-organic frameworks

NC Chiu, JM Lessard, EN Musa, LS Lancaster… - Nature …, 2024 - nature.com
Abstract Here, four MOFs, namely Sc-TBAPy, Al-TBAPy, Y-TBAPy, and Fe-TBAPy (TBAPy: 1,
3, 6, 8-tetrakis (p-benzoic acid) pyrene), were characterized and evaluated for their ability to …

Full-spectrum photocatalytic treatment and in situ upcycling of organophosphorus wastewater enabled by biomimetic urchin-like Bi2S3/CdS

T Liu, J Huang, Z Huang, Q Luo, H Wu, Y Meng… - Chemical Engineering …, 2024 - Elsevier
High-efficiency photo-degradation organophosphorus pollutants into value-added
chemicals, reducing or avoiding CO 2 emission, is challenging but significant for …

Adaptive lattice-matched MOF and COF core-shell heterostructure for carbon dioxide photoreduction

X Yu, J Li, M Du, X Song, H Huang, L Nie - Cell Reports Physical Science, 2023 - cell.com
Rational design of photocatalysts is critical for efficient solar-light-driven carbon dioxide
reduction. The conjugation of metal-organic framework (MOF) and covalent organic …

Metal–Organic Frameworks in General Chemistry Laboratory: Toward the Development of Students' Scientific Identities

K Bach, RP Loughran, A Johnson… - Journal of Chemical …, 2024 - ACS Publications
Metal–organic frameworks (MOFs) are porous materials composed of metal ions and
organic ligands. These materials have garnered significant attention due to their wide …

Full Electron Delocalization across the Cluster in 1,12-bisBMes2-p-carborane Radical Anion

L Wu, X Zhang, M Moos, I Krummenacher… - Journal of the …, 2024 - ACS Publications
Conjugation between three-dimensional (3D) carboranes and the attached substituents is
commonly believed to be very weak. In this paper, we report that reducing 1, 12-bis (BMes2) …

Recent Advances in Photocatalytic Nanomaterials for Environmental Remediation: Strategies, Mechanisms, and Future Directions

X Zhang, S Xiong, A Sathiyaseelan, L Zhang, Y Lu… - Chemosphere, 2024 - Elsevier
Innovative and efficient strategies are urgently needed for wastewater treatment and
environmental remediation. The photocatalytic degradation properties of photo-responsive …

Bioinspired Heterocoordination in Adaptable Cobalt Metal–Organic Framework for DNA Epigenetic Modification Detection

Z Wei, L Yu, Y Feng, Z Gan, Y Shen, S Peng… - Analytical …, 2024 - ACS Publications
Metal–organic frameworks (MOFs) show unique advantages in simulating the dynamics and
fidelity of natural coordination. Inspired by zinc finger protein, a second linker was …

Gas Adsorption Snapshots in Metal–Organic Frameworks Unveil the Impact of Pore Geometry on Hydrogen Storage

NC Chiu, A Gładysiak, AK Yadav… - ACS Materials …, 2024 - ACS Publications
Metal–organic frameworks (MOFs) are promising candidates for hydrogen (H2) storage.
However, effective H2 storage in MOFs is challenging, because of weak adsorbent …