Silicon-stereogenic chiral organosilanes have found increasing applications in synthetic
chemistry, medicinal chemistry, and materials science. In this context, various asymmetric …

Silacycles have exhibited significant potential for application in the fields of medicinal
chemistry, agrochemistry, and materials science. Accordingly, the development of effective …

Despite impressive advances in the construction of enantioenriched silacarbocycles
featuring silicon‐stereogenic centers via a selection of well‐defined sila‐synthons, the …

Enantiopure Si-stereogenic organosilanes are highly valued in the fields of organic
synthesis, development of advanced materials, and drug discovery. However, they are not …

An efficient cross-electrophile couplings of aryl fluorosulfates with vinyl chlorosilanes by
using nickel as transition metal catalyst and manganese as reductant has been achieved …

Transition metal-catalyzed reductive cross-couplings to build C–C/Si bonds have been
developed, but the reductive cross-coupling to create the C (sp2)–B bond has not been …

Transition metal‐catalyzed direct decarboxylative transformations of aromatic carboxylic
acids usually require high temperatures, which limit the substrate's scope, especially for late …

We report a highly enantioselective intermolecular C− H bond silylation catalyzed by a
phosphoramidite‐ligated iridium catalyst. Under reagent‐controlled protocols …

In this study, we present a nickel-catalyzed reductive C (sp3)–Sb coupling of unactivated
alkyl chlorides with chlorostibines. This approach is highly versatile, tolerating various …

While significant progress has been made in the area of transition metal‐catalyzed ring‐
opening and formal cycloaddition reactions of 1, 1‐disubstituted silacyclobutanes (SCBs) …