Atomic spectrometry update: review of advances in the analysis of metals, chemicals and materials
S Carter, R Clough, A Fisher, B Gibson… - Journal of Analytical …, 2022 - pubs.rsc.org
This update covers the literature published between approximately June 2021 and May
2022 and is the latest part of a series of annual reviews. It is designed to provide the reader …
2022 and is the latest part of a series of annual reviews. It is designed to provide the reader …
Size Dependence of Lattice Parameter and Electronic Structure in CeO2 Nanoparticles
D Prieur, W Bonani, K Popa, O Walter… - Inorganic …, 2020 - ACS Publications
Intrinsic properties of a compound (eg, electronic structure, crystallographic structure, optical
and magnetic properties) define notably its chemical and physical behavior. In the case of …
and magnetic properties) define notably its chemical and physical behavior. In the case of …
[PDF][PDF] ROBL-II at ESRF: a synchrotron toolbox for actinide research
AC Scheinost, J Claussner, J Exner… - Journal of …, 2021 - journals.iucr.org
ROBL-II provides four different experimental stations to investigate actinide and other alpha-
and beta-emitting radionuclides at the new EBS storage ring of ESRF within an energy …
and beta-emitting radionuclides at the new EBS storage ring of ESRF within an energy …
X-ray absorption spectra of f-element complexes: insight from relativistic multiconfigurational wavefunction theory
DC Sergentu, J Autschbach - Dalton Transactions, 2022 - pubs.rsc.org
X-ray absorption near edge structure (XANES) spectroscopy, coupled with ab initio
calculations, has emerged as the state-of-the-art tool for elucidating the metal-ligand …
calculations, has emerged as the state-of-the-art tool for elucidating the metal-ligand …
Covalency in actinide (IV) hexachlorides in relation to the chlorine K-edge X-ray absorption structure
DC Sergentu, J Autschbach - Chemical Science, 2022 - pubs.rsc.org
Chlorine K-edge X-ray absorption near edge structure (XANES) in actinideIV
hexachlorides,[AnCl6] 2−(An= Th–Pu), is calculated with relativistic multiconfiguration …
hexachlorides,[AnCl6] 2−(An= Th–Pu), is calculated with relativistic multiconfiguration …
The missing pieces of the PuO 2 nanoparticle puzzle
The nanoscience field often produces results more mystifying than any other discipline. It
has been argued that changes in the plutonium dioxide (PuO2) particle size from bulk to …
has been argued that changes in the plutonium dioxide (PuO2) particle size from bulk to …
Probing the local structure of nanoscale actinide oxides: a comparison between PuO 2 and ThO 2 nanoparticles rules out PuO 2+ x hypothesis
Actinide research at the nanoscale is gaining fundamental interest due to environmental and
industrial issues. The knowledge of the local structure and speciation of actinide …
industrial issues. The knowledge of the local structure and speciation of actinide …
Synthesis and multi-scale properties of PuO 2 nanoparticles: recent advances and open questions
Due to the increased attention given to actinide nanomaterials, the question of their structure–
property relationship is on the spotlight of recent publications. Plutonium oxide (PuO2) …
property relationship is on the spotlight of recent publications. Plutonium oxide (PuO2) …
Relevance of formation conditions to the size, morphology and local structure of intrinsic plutonium colloids
Fundamental knowledge about plutonium intrinsic colloids is a key issue for the prediction of
plutonium transport and release rates in the environment. Recent studies demonstrated that …
plutonium transport and release rates in the environment. Recent studies demonstrated that …
The Application of HEXS and HERFD XANES for Accurate Structural Characterisation of Actinide Nanomaterials: The Case of ThO2
The structural characterisation of actinide nanoparticles (NPs) is of primary importance and
hard to achieve, especially for non‐homogeneous samples with NPs less than 3 nm. By …
hard to achieve, especially for non‐homogeneous samples with NPs less than 3 nm. By …