Heme proteins utilize the heme cofactor, an iron porphyrin, to perform a diverse range of
reactions including dioxygen binding and transport, electron transfer, and oxidation …

Conspectus A large class of heme and non-heme metalloenzymes utilize O2 or its
derivatives (eg, H2O2) to generate high-valent metal–oxo intermediates for performing …

Homogenous catalysis technology could be flexibly combined with existing water treatment
facilities, which presents broad applicational prospects and deserves systematic study. This …

Designing a stable and selective catalyst with high H2 utilisation is of pivotal importance for
the direct gas‐phase epoxidation of propylene. This work describes a facile one‐pot …

The de-novo synthesis of soluble or solid-supported Pd-(CaCO 3) n clusters (n= 2–13) and
their high catalytic activity for the semi-hydrogenation of internal alkynes compared to …

Metal–oxo moieties are important catalytic intermediates in the selective partial oxidation of
hydrocarbons and in water splitting. Stable metal–oxo species have reactive properties that …

The synthesis and characterization of the Schiff base complexes Fe (II)(2M) and Fe (III) Cl
(3M), where M is a K+ or Ba2+ ion incorporated into the ligand, are reported. The Fe (III/II) …

Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …

The ongoing pattern shift in water treatment from pollution control to energy recovery
challenges the energy-intensive chemical oxidation processes that have been developed for …

μ-Nitrido-bridged diiron porphyrins and phthalocyanines are known to be efficient oxidants
that are able to oxidize some of the strongest C–H bonds in nature, such as the one in …