Chirality in adsorption on solid surfaces

F Zaera - Chemical Society Reviews, 2017 - pubs.rsc.org
In the present review we survey the main advances made in recent years on the
understanding of chemical chirality at solid surfaces. Chirality is an important topic, made …

Chiral metal surfaces for enantioselective processes

N Shukla, AJ Gellman - Nature Materials, 2020 - nature.com
Chiral surfaces are critical components of enantioselective heterogeneous processes such
as those used to prepare enantiomerically pure pharmaceuticals. While the majority of chiral …

Recognition at chiral interfaces: From molecules to cells

Y Ma, L Shi, H Yue, X Gao - Colloids and Surfaces B: Biointerfaces, 2020 - Elsevier
As a ubiquitous phenomenon in nature, chirality plays a pivotal role in a variety of biological
and physiological processes. The construction of chiral interfaces and exploration of their …

Epitaxial electrodeposition of chiral metal surfaces on silicon (643)

MV Kelso, JZ Tubbesing, Q Chen… - Journal of the American …, 2018 - ACS Publications
Surfaces of achiral materials exhibit two-dimensional chirality if they lack mirror symmetry.
An example is the (643) surface of face-centered-cubic metals such as Au. The (643) and …

[HTML][HTML] Recent advances in the use of curved single crystal surfaces

SV Auras, LBF Juurlink - Progress in Surface Science, 2021 - Elsevier
In surface science, research traditionally employs macroscopically flat surfaces of single
crystals. Curved surfaces have been applied more sporadically, but their history stretches …

Structure Sensitive Reaction Kinetics of Chiral Molecules on Intrinsically Chiral Surfaces

K Abdelmaqsoud, M Radetic… - The Journal of …, 2024 - ACS Publications
Enantiospecific heterogeneous catalysis utilizes chiral surfaces to resolve enantiomers via
structure sensitive surface chemistry. The catalyst design challenge is the identification of …

Atomic-scale origin of the enantiospecific decomposition of tartaric acid on chiral copper surfaces

AS Daniels, AJ Gellman, ECH Sykes - Chemical Communications, 2024 - pubs.rsc.org
The origin of the enantiospecific decomposition of L-and D-tartaric acid on chiral Cu
surfaces is elucidated on a structure-spread domed Cu (110) crystal by spatially resolved …

Initiation of vacancy-mediated, surface explosion reactions: tartaric and aspartic acid on Cu Surfaces

P Kondratyuk, B Karagoz, Y Yun… - The Journal of Physical …, 2019 - ACS Publications
Surface explosion reactions have highly nonlinear reaction kinetics that exhibit
autoacceleration under isothermal conditions. These can lead to phenomena such as …

[HTML][HTML] Recent progress in fabrication and application of chiral interfaces

LIU Qixin, Y ZHANG, WU Lie, X JIANG - Chinese Journal of Analytical …, 2024 - Elsevier
Chirality, also known as handedness, is one of the most widespread and intriguing
properties in nature, touching upon various fields including physics, chemistry, biology …

Steady-state catalytic decomposition of aspartic acid on Cu (111)

Y Yun, P Kondratyuk, AJ Gellman - The Journal of Physical …, 2018 - ACS Publications
Decomposition of tartaric acid (TA, HO2CCH (OH) CH (OH) CO2H) and aspartic acid (Asp,
HO2CCH (NH2) CH2CO2H) on Cu surfaces occurs via a vacancy-mediated surface …