Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Earth-abundant Fe, Ni, and Co aza macrocyclic and polypyridine complexes have been
thoroughly investigated for CO2 electrochemical and visible-light-driven reduction. Since the …

The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

Electrosynthesis is a popular, green alternative to traditional organic methods.
Understanding the mechanisms is not trivial yet is necessary to optimize reaction processes …

Although iron is a dream candidate to substitute noble metals in photoactive complexes,
realization of emissive and photoactive iron compounds is demanding due to the fast …

Photocatalytic conversion of CO2 into carbonaceous feedstock chemicals is a promising
strategy to mitigate greenhouse gas emissions and simultaneously store solar energy in …

A detailed mechanistic study of the electrochemical CO2 reduction catalyzed by the fac-[MnI
(CO) 3 (bis-MeNHC) MeCN]+ complex (1-MeCN+) is reported herein by combining in situ …

The ability to obtain a molecular-level understanding of the chemistry that takes place at
liquid/solid interfaces is key to the development and improvement of many chemical and …

The controlled electrochemical reduction of carbon dioxide to value added chemicals is an
important strategy in terms of renewable energy technologies. Therefore, the development of …

Infrared absorption spectroscopy has proven to be one of the most powerful spectroscopic
techniques available for the characterization of catalytic systems. Although the history of IR …