Photoactivated artificial molecular motors

S Corra, M Curcio, A Credi - JACS Au, 2023 - ACS Publications
Accurate control of long-range motion at the molecular scale holds great potential for the
development of ground-breaking applications in energy storage and bionanotechnology …

Controllable photomechanical bending of metal-organic rotaxane crystals facilitated by regioselective confined-space photodimerization

J Geng, L Mei, Y Liang, L Yuan, J Yu, K Hu… - Nature …, 2022 - nature.com
Molecular machines based on mechanically-interlocked molecules (MIMs) such as (pseudo)
rotaxanes or catenates are known for their molecular-level dynamics, but promoting macro …

Modulation of Rotational Dynamics in Halogen-Bonded Cocrystalline Solids

SS Gunaga, DL Bryce - Journal of the American Chemical Society, 2023 - ACS Publications
Dynamic processes are responsible for the functionality of a range of materials,
biomolecules, and catalysts. We report a detailed systematic study of the modulation of …

Time-dependent solvent-driven solid-state fluorescence-based numeric coding

YD Yang, XL Chen, J Liang, JW Fang… - Journal of the …, 2023 - ACS Publications
Controllable solid-state transformations can provide a basis for novel functional materials.
Herein, we report a series of solid-state systems that can be readily transformed between …

Dynamic network of intermolecular interactions in metal-organic frameworks functionalized by molecular machines

E Kolodzeiski, S Amirjalayer - Science Advances, 2022 - science.org
Molecular machines enable external control of structural and dynamic phenomena at the
atomic level. To efficiently transfer their tunable properties into designated functionalities, a …

Mechanical Bonding as a Promoter of Crystalline Diversity in Halogenated [2] Rotaxanes

T Orlando, JM Perez, FFS Farias… - Crystal Growth & …, 2023 - ACS Publications
Understanding the nature of the mechanical bond is critical to advancing the design of novel
mechanically interlocked molecules. Given that numerous applications of new materials are …

Light-responsive rotaxane-based materials: inducing motion in the solid state

A Saura-Sanmartin - Beilstein Journal of Organic Chemistry, 2023 - beilstein-journals.org
Light-responsive rotaxane-based solid-state materials are ideal scaffolds in order to develop
smart materials due to the properties provided by the mechanical bond, such as control over …