Switchable metallacycles and metallacages
Two-dimensional metallacycles and three-dimensional metallacages constructed by
coordination-driven self-assembly have attracted much attention because they exhibit …
coordination-driven self-assembly have attracted much attention because they exhibit …
Transformation networks of metal–organic cages controlled by chemical stimuli
E Benchimol, BNT Nguyen, TK Ronson… - Chemical Society …, 2022 - pubs.rsc.org
The flexibility of biomolecules enables them to adapt and transform as a result of signals
received from the external environment, expressing different functions in different contexts …
received from the external environment, expressing different functions in different contexts …
Dynamic Metallosupramolecular Cages Containing 12 Adaptable Pockets for High-Order Guest Binding Beyond Biomimicry
YH Huang, YL Lu, J Ruan, SP Zheng… - Journal of the …, 2023 - ACS Publications
Molecular recognition lies at the heart of biological functions, which inspires lasting research
in artificial host syntheses to mimic biomolecules that can recognize, process, and transport …
in artificial host syntheses to mimic biomolecules that can recognize, process, and transport …
Systematic construction of progressively larger capsules from a fivefold linking pyrrole-based subcomponent
Biological encapsulants, such as viral capsids and ferritin protein cages, use many identical
subunits to tile the surface of a polyhedron. Inspired by these natural systems, synthetic …
subunits to tile the surface of a polyhedron. Inspired by these natural systems, synthetic …
Constructing Ultrastable Metallo-Cages via In Situ Deprotonation/Oxidation of Dynamic Supramolecular Assemblies
Coordination-driven self-assembly enables the spontaneous construction of metallo-
supramolecules with high precision, facilitated by dynamic and reversible metal–ligand …
supramolecules with high precision, facilitated by dynamic and reversible metal–ligand …
New insights and discoveries in anion receptor chemistry
DA McNaughton, WG Ryder, AM Gilchrist, P Wang… - Chem, 2023 - cell.com
This review offers a broad overview of the advancements in anion receptor chemistry in
2021 and 2022. Detailed examples of acclaimed work in fundamental recognition, sensing …
2021 and 2022. Detailed examples of acclaimed work in fundamental recognition, sensing …
Fluoride up-and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages
The development of artificial molecular systems capable of allosteric regulation has the
potential to unlock new functions related to the purification, sensing, and transformation of …
potential to unlock new functions related to the purification, sensing, and transformation of …
Metallo-supramolecular hexagonal wreath with four switchable states based on a pH-responsive tridentate ligand
P Su, B Wei, C Guo, Y Hu, R Tang… - Journal of the …, 2023 - ACS Publications
In biological systems, many biomacromolecules (eg, heme proteins) are capable of
switching their states reversibly in response to external stimuli, endowing these natural …
switching their states reversibly in response to external stimuli, endowing these natural …
Construction of a molecular prime link by interlocking two trefoil knots
Z Cui, GX Jin - Nature Synthesis, 2022 - nature.com
Simple and efficient synthetic routes to topologically complex mechanically interlocked
molecules remain scarce owing to the sophisticated three-dimensional entanglement of their …
molecules remain scarce owing to the sophisticated three-dimensional entanglement of their …
Modular Construction of a Tessellated Octahedron, its Hierarchical Spherical Aggregate Behavior, and Electrocatalytic CO2 Reduction Activity
G Wang, Y Yang, H Liu, M Chen, Z Jiang… - Angewandte Chemie …, 2022 - Wiley Online Library
Coordination‐driven self‐assembly has led to the formation of various aesthetical
polyhedrons and compounds with advanced functions. Whereas two‐dimensional …
polyhedrons and compounds with advanced functions. Whereas two‐dimensional …