Functionalization of pyrene to prepare luminescent materials—typical examples of synthetic methodology

X Feng, JY Hu, C Redshaw… - Chemistry–A European …, 2016 - Wiley Online Library
Pyrene‐based π‐conjugated materials are considered to be an ideal organic electro‐
luminescence material for application in semiconductor devices, such as organic light …

Devising efficient red‐shifting strategies for bioimaging: A generalizable donor‐acceptor fluorophore prototype

C Chen, C Fang - Chemistry–An Asian Journal, 2020 - Wiley Online Library
Long emission wavelengths, high fluorescence quantum yields (FQYs), and large Stokes
shifts are highly desirable features for fluorescent probes in biological imaging. However …

Pyrene molecular orbital shuffle—controlling excited state and redox properties by changing the nature of the frontier orbitals

J Merz, J Fink, A Friedrich… - … A European Journal, 2017 - Wiley Online Library
We show that by judicious choice of substituents at the 2‐and 7‐positions of pyrene, the
frontier orbital order of pyrene can be modified, giving enhanced control over the nature and …

A–π–D–π–A carbazole derivatives with remarkable solvatochromism and mechanoresponsive luminescence turn-on

P Wen, Z Gao, R Zhang, A Li, F Zhang, J Li… - Journal of Materials …, 2017 - pubs.rsc.org
Two A–π–D–π–A molecules with a carbazole donor and a dicyanovinyl acceptor but
differing in N-hexyl (h-CPDM) and N-isooctyl substituents (i-CPDM) were synthesized, and …

A modular fluorescent probe for viscosity and polarity sensing in DNA hybrid mesostructures

S Ludwanowski, A Samanta, S Loescher… - Advanced …, 2021 - Wiley Online Library
There exists a critical need in biomedical molecular imaging and diagnostics for molecular
sensors that report on slight changes to their local microenvironment with high spatial …

Bright red-emitting pyrene derivatives with a large Stokes shift for nucleus staining

CS Abeywickrama, KJ Wijesinghe… - Chemical …, 2017 - pubs.rsc.org
A highly fluorescent red-emitting pyrene derivative was synthesized and found to exhibit a
large Stokes shift (λem≈ 610 nm, Δλ∼ 130 nm, Δν∼ 4597 cm− 1). The probe molecule …

Push–pull dioxaborine as fluorescent molecular rotor: far-red fluorogenic probe for ligand–receptor interactions

J Karpenko, Y Niko, VP Yakubovskyi… - Journal of Materials …, 2016 - pubs.rsc.org
Fluorescent solvatochromic dyes and molecular rotors have attracted considerable attention
as fluorogenic probes because of background-free detection of biomolecules in live cells in …

Synthesis, Photophysical and Electronic Properties of New Red‐to‐NIR Emitting Donor–Acceptor Pyrene Derivatives

J Merz, M Dietz, Y Vonhausen, F Wöber… - … A European Journal, 2020 - Wiley Online Library
We synthesized new pyrene derivatives with strong bis (para‐methoxyphenyl) amine donors
at the 2, 7‐positions and n‐azaacene acceptors at the K‐region of pyrene. The compounds …

Dynamic spin–spin interaction observed as interconversion of chemical bonds in stepwise two-photon induced photochromic reaction

K Mutoh, S Toshimitsu, Y Kobayashi… - Journal of the American …, 2021 - ACS Publications
Biradicaloids in π-conjugated organic molecules have been extensively studied in recent
years because of the fundamental insights into the chemical bonds and unique optical …

Synthesis and Properties of 4-and 10-Benzoyl-1-azapyrenes

A Vardanyan, MA Argüello Cordero… - The Journal of …, 2024 - ACS Publications
A series of 4-and 10-benzoyl-1-azapyrenes were prepared by a combination of Pd-
catalyzed cross-coupling reactions and Brønsted-acid-mediated alkyne-carbonyl-metathesis …