In recent years, the activation of unactivated alkyl chlorides through light-induced processes
has emerged as a promising field in radical chemistry, and has led to new transformations in …

The employment of light and/or electricity–alternatively to conventional thermal energy–
unlocks new reactivity paradigms as tools for chemical substrate activations. This leads to …

Unveiling the alkyl/Pd hybrid species is a unique sp3-C-centered radical for facilitating
intermolecular hydrogen atom transfer (HAT) in the development of direct alkylation of …

Visible light‐induced Pd catalysis has emerged as a promising subfield of photocatalysis.
The hybrid nature of Pd radical species has enabled a wide array of radical‐based …

We describe a visible-light photoredox-catalyzed alkylation/arylative cyclization of N-
acrylamides─ from 2-arylindoles, 2-arylbenzimidazoles, or N-substituted anilines─ with …

Abstract Photocatalytic selective C (sp3)–H activation/cross-coupling reactions are
appealing in organic synthesis. In this manuscript, we describe the development of …

A visible-light-mediated oxidative cyclization of N-arylacrylamides by a radical cascade with
readily available aliphatic or aromatic aldehydes was achieved. This transformation …

A photoinduced palladium-catalyzed desaturation method that is suitable for converting the
linear amides to their α, β-unsaturated counterparts is reported. The reaction does not …

Reactions of unactivated alkyl chlorides under mild and sustainable conditions are rare
compared to those of alkyl bromides or iodides. As a result, synthetic methods capable of …

Palladium catalysis induced by visible-light irradiation is a promising tool for promoting
unusual chemical transformations. We describe the development of excited-state palladium …