Selective hydrogenation of nitro compounds to amines by coupled redox reactions over a heterogeneous biocatalyst

D Sokolova, TC Lurshay, JS Rowbotham… - Nature …, 2024 - nature.com
Cleaner synthesis of amines remains a key challenge in organic chemistry because of their
prevalence in pharmaceuticals, agrochemicals and synthetic building blocks. Here, we …

Reusable Cobalt-Catalyzed Selective Transfer Hydrogenation of Azoarenes and Nitroarenes

S Dey, D Panja, A Sau, SD Thakur… - The Journal of Organic …, 2023 - ACS Publications
Herein, control transfer hydrogenation (TH) of azoarenes to hydrazo compounds is
established employing easy-to-synthesize reusable cobalt catalyst using lower amounts of …

Heterogeneous V2O5/TiO2-Mediated Photocatalytic Reduction of Nitro Compounds to the Corresponding Amines under Visible Light

S Kumar, SK Maurya - The Journal of Organic Chemistry, 2023 - ACS Publications
The hydrogenation of nitro compounds to their corresponding amines is developed using a
heterogeneous and recyclable catalyst (V2O5/TiO2) under irradiation of blue LED (9 W) at …

Bimetallic Porphyrin Metal–Organic Framework as Photocatalyst for Red-Light-Driven Selective Reduction of Nitroarenes to Aromatic Amines

SL Kang, T Yue, DD Su, WJ Shi, PC Jiang… - ACS Sustainable …, 2024 - ACS Publications
It is a great challenge to construct a green catalytic system for the reduction of nitro
compounds to the corresponding amines under mild conditions. Due to the low energy of …

Visible-light-induced iron-catalyzed reduction of nitroarenes to anilines

S Yang, M He, Y Wang, M Bao, X Yu - Chemical Communications, 2023 - pubs.rsc.org
An efficient visible-light-induced iron-catalyzed reduction of nitroarenes to anilines by using
N-ethylmorpholine (NEM) as a reductant under mild conditions has been developed. The …

High turnover and selective Bin-Pd-NCs catalyst for nitro group non-hydrogen reductions in H2O under air conditions: A sustainable and recyclable route to aromatic …

YT Xia, X Wang, MH Su, JY Zhou, DX Guo, BP Zhang… - Journal of …, 2024 - Elsevier
A green synthesis of anilines by the non-hydrogen reduction of nitro compounds is
described. The reaction and post-treatment purification processes can produce high-purity …

A high-valent Ru-PCP pincer catalyst for hydrosilylation reactions

S Mujahed, D Gandolfo, L Vaccaro, E Kirillov… - Molecular …, 2024 - Elsevier
In this communication, we report on successfully applying a high-valent Ru (IV) bifunctional
catalyst (1) for the hydrosilylation of carbonyl compounds, carboxylic acids, esters, nitriles …

Cobalt catalyzed chemoselective reduction of nitroarenes: hydrosilylation under thermal and photochemical reaction conditions

S Panda, A Nanda, RR Behera, R Ghosh… - Chemical …, 2023 - pubs.rsc.org
Commercially available Co2 (CO) 8 was used as an effective catalyst for the hydrosilylation
of nitroarenes under both thermal and photochemical conditions. A wide variety of …

Copper (i)-catalyzed click chemistry in deep eutectic solvent for the syntheses of β-d-glucopyranosyltriazoles

S Sethi, NC Jana, S Panda, SK Maharana, B Bagh - RSC advances, 2023 - pubs.rsc.org
In the last two decades, click chemistry has progressed as a powerful tool in joining two
different molecular units to generate fascinating structures with a widespread application in …

Hydrosilylation of Terminal Alkynes Catalyzed by an Air-Stable Manganese–NHC Complex

RR Behera, R Saha, AA Kumar, S Sethi… - The Journal of …, 2023 - ACS Publications
In recent years, catalysis with base metal manganese has received a significant amount of
interest. Catalysis with manganese complexes having N-heterocyclic carbenes (NHCs) is …