Utilization of methylarenes as versatile building blocks in organic synthesis

R Vanjari, KN Singh - Chemical Society Reviews, 2015 - pubs.rsc.org
The development of practical and efficient methods for C–C and C–X bond formation has
attracted a great deal of current attention with the advent of C–H functionalization reactions …

[HTML][HTML] Cross-dehydrogenative coupling for the intermolecular C–O bond formation

IB Krylov, VA Vil, AO Terent'ev - Beilstein journal of organic …, 2015 - beilstein-journals.org
The present review summarizes primary publications on the cross-dehydrogenative C–O
coupling, with special emphasis on the studies published after 2000. The starting …

Copper-Catalyzed Remote C(sp3)–H Phosphorothiolation of Sulfonamides and Carboxamides in a Multicomponent Reaction

S Shi, P Zhang, C Luo, S Zhuo, Y Zhang, G Tang… - Organic …, 2020 - ACS Publications
The catalytic C (sp3)–H functionalization is highly desirable yet challenging in organic
synthesis. Incorporation of the SP (O)(OR) 2 group through C (sp3)–H functionalization …

Azidation in the Difunctionalization of Olefins

K Wu, Y Liang, N Jiao - Molecules, 2016 - mdpi.com
Organic azides are key motifs in compounds of relevance to chemical biology, medicinal
chemistry and materials science. In addition, they also serve as useful building blocks due to …

Visible-light-mediated α-phosphorylation of N-aryl tertiary amines through the formation of electron-donor–acceptor complexes: synthetic and mechanistic studies

V Quint, N Chouchène, M Askri, J Lalevée… - Organic Chemistry …, 2019 - pubs.rsc.org
This work describes an efficient α-phosphorylation of a wide variety of N-aryl tertiary amines
under mild conditions. It consists of a simple combination of amines (electron donors) with N …

tert-Butyl Hydroperoxide Mediated Cascade Synthesis of 3-Arylsulfonylquinolines

L Zhang, S Chen, Y Gao, P Zhang, Y Wu, G Tang… - Organic …, 2016 - ACS Publications
3-Arylsulfonylquinoline derivatives play important roles as pharmaceutical drugs. A new
method for the synthesis of 3-arylsulfonylquinoline derivatives has been achieved through …

Cascade arylalkylation of activated alkenes: synthesis of chloro-and cyano-containing oxindoles

X Li, J Xu, Y Gao, H Fang, G Tang… - The Journal of Organic …, 2015 - ACS Publications
The general method for the oxidative cyclization of arylacrylamides with dichloromethane or
acetonitrile has been developed. The reactions described provide novel access to chloro …

Cobalt-Catalyzed Oxidative C(sp3)–H Phosphonylation for α-Aminophosphonates via C(sp3)–H/P(O)–H Coupling

B Lin, S Shi, R Lin, Y Cui, M Fang… - The Journal of Organic …, 2018 - ACS Publications
The first oxidative C (sp3)–H phosphonylation of tertiary aliphatic amines has been
developed. The use of cobalt acetate as a catalyst, N-hydroxyphthalimide as a cocatalyst …

Iodide‐Catalyzed Phosphorothiolation of Heteroarenes Using P (O) H Compounds and Elemental Sulfur

S Shi, J Chen, S Zhuo, Z Wu, M Fang… - Advanced Synthesis …, 2019 - Wiley Online Library
Organothiophosphates have found widespread application as biologically active
compounds and synthetic intermediates in medicinal chemistry. The first transition‐metal …

Dehydrogenative coupling involving P (O)–H bonds: a powerful way for the preparation of phosphoryl compounds

T Chen, JS Zhang, LB Han - Dalton Transactions, 2016 - pubs.rsc.org
Because of the unique properties and wide applications, continuing efforts have been
devoted to developing simpler and cleaner methods for the synthesis of organophosphorus …