TeraChem: A graphical processing unit‐accelerated electronic structure package for large‐scale ab initio molecular dynamics

S Seritan, C Bannwarth, BS Fales… - Wiley …, 2021 - Wiley Online Library
TeraChem was born in 2008 with the goal of providing fast on‐the‐fly electronic structure
calculations to facilitate ab initio molecular dynamics studies of large biochemical systems …

The ground state electronic energy of benzene

JJ Eriksen, TA Anderson, JE Deustua… - The journal of …, 2020 - ACS Publications
We report on the findings of a blind challenge devoted to determining the frozen-core, full
configuration interaction (FCI) ground-state energy of the benzene molecule in a standard …

The static–dynamic–static family of methods for strongly correlated electrons: methodology and benchmarking

Y Song, Y Guo, Y Lei, N Zhang, W Liu - New Horizons in Computational …, 2022 - Springer
A series of methods (SDSCI, SDSPT2, iCI, iCIPT2, iCISCF (2), iVI, and iCAS) is introduced to
accurately describe strongly correlated systems of electrons. Born from the (restricted) static …

[HTML][HTML] TeraChem: Accelerating electronic structure and ab initio molecular dynamics with graphical processing units

S Seritan, C Bannwarth, BS Fales… - The Journal of …, 2020 - pubs.aip.org
Developed over the past decade, TeraChem is an electronic structure and ab initio
molecular dynamics software package designed from the ground up to leverage graphics …

Iterative configuration interaction with selection

N Zhang, W Liu, MR Hoffmann - Journal of Chemical Theory and …, 2020 - ACS Publications
Even when starting with very poor initial guess, the iterative configuration interaction (iCI)
approach [J. Chem. Theory Comput. 12, 1169 (2016)] for strongly correlated electrons can …

[HTML][HTML] CAS without SCF—Why to use CASCI and where to get the orbitals

BG Levine, AS Durden, MP Esch, F Liang… - The Journal of Chemical …, 2021 - pubs.aip.org
The complete active space self-consistent field (CASSCF) method has seen broad adoption
due to its ability to describe the electronic structure of both the ground and excited states of …

The shape of full configuration interaction to come

JJ Eriksen - The Journal of Physical Chemistry Letters, 2020 - ACS Publications
We present a Perspective on what the future holds for full configuration interaction (FCI)
theory, with an emphasis on conceptual rather than technical details. Upon revisiting the …

[HTML][HTML] An efficient implementation of the NEVPT2 and CASPT2 methods avoiding higher-order density matrices

C Kollmar, K Sivalingam, Y Guo… - The Journal of Chemical …, 2021 - pubs.aip.org
A factorization of the matrix elements of the Dyall Hamiltonian in N-electron valence state
perturbation theory allowing their evaluation with a computational effort comparable to the …

Distributed implementation of full configuration interaction for one trillion determinants

H Gao, S Imamura, A Kasagi… - Journal of Chemical …, 2024 - ACS Publications
Full configuration interaction (FCI) can provide an exact molecular ground-state energy
within a given basis set and serve as a benchmark for approximate methods in quantum …

Further development of iCIPT2 for strongly correlated electrons

N Zhang, W Liu, MR Hoffmann - Journal of Chemical Theory and …, 2021 - ACS Publications
The efficiency of the recently proposed iCIPT2 [iterative configuration interaction (iCI) with
selection and second-order perturbation theory (PT2); J. Chem. Theory Comput. 2020, 16 …