Adsorchromism: Molecular nanoarchitectonics at 2D nanosheets—Old chemistry for advanced chromism
Chromism induced by changes in the electronic states of dye molecules due to surface
adsorption is termed “adsorchromism” in this article. These changes of molecular electronic …
adsorption is termed “adsorchromism” in this article. These changes of molecular electronic …
Designed nanostructures of clay for controlled adsorption of organic compounds
The utilization of smectite clay, swelling layered silicate, as scaffolds for designing functional
nanostructures was overviewed. Surface modification of smectites with organoammonium …
nanostructures was overviewed. Surface modification of smectites with organoammonium …
Size-matching effect on inorganic nanosheets: control of distance, alignment, and orientation of molecular adsorption as a bottom-up methodology for nanomaterials
We have been investigating complexes composed of nanolayered materials with anionic
charges such as clay nanosheets and dye molecules such as cationic porphyrins. It was …
charges such as clay nanosheets and dye molecules such as cationic porphyrins. It was …
“Surface-fixation induced emission” of porphyrazine dye by a complexation with inorganic nanosheets
This paper proposes a unique phenomenon of the strong enhancement in the fluorescence
quantum yield (φf) and the excited lifetime (τ) of tetra-cationic porphyrazine dye (Pz) upon a …
quantum yield (φf) and the excited lifetime (τ) of tetra-cationic porphyrazine dye (Pz) upon a …
Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping
Partial replacement of one structural element in a solid with another of a similar size was
conducted to impart functionality to the solids and modify their properties. This phenomenon …
conducted to impart functionality to the solids and modify their properties. This phenomenon …
Manipulation of precise molecular arrangements and their photochemical properties on inorganic surfaces via multiple electrostatic interactions
Y Ishida - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Multiple (or multivalent) interaction is the key in many biological systems. One of the most
important (photo-) chemical reactions, photosynthesis, is driven by regularly aligned …
important (photo-) chemical reactions, photosynthesis, is driven by regularly aligned …
Photophysical properties and adsorption behaviors of novel tri-cationic boron (III) subporphyrin on anionic clay surface
T Tsukamoto, T Shimada, S Takagi - ACS Applied Materials & …, 2016 - ACS Publications
Two types of+ 3-charged subporphyrin derivatives with m-and p-methylpyridinium as the
meso-aryl substituents were designed and synthesized. Their photophysical properties with …
meso-aryl substituents were designed and synthesized. Their photophysical properties with …
Efficient singlet–singlet energy transfer in a novel host–guest assembly composed of an organic cavitand, aromatic molecules, and a clay nanosheet
A supramolecular host–guest assembly composed of a cationic organic cavitand (host),
neutral aromatic molecules (guests), and an anionic clay nanosheet has been prepared and …
neutral aromatic molecules (guests), and an anionic clay nanosheet has been prepared and …
Effects of the surface charge density of clay minerals on surface-fixation induced emission of acridinium derivatives
Surface-fixation induced emission is a fluorescence enhancement phenomenon, which is
expressed when dye molecules satisfy a specific adsorption condition on the anionic clay …
expressed when dye molecules satisfy a specific adsorption condition on the anionic clay …
The Unique Structure–Activity Relationship of Porphyrins and Clay Mineral Systems in Modern Applications: A Comprehensive Review
JH Hassen, J Silver - Chemical and Biochemical Engineering Quarterly, 2024 - hrcak.srce.hr
Sažetak Porphyrins are a group of organic heterocyclic macromolecules, composed of four
modified pyrrole subunits interconnected at their α carbon atoms via methine bridges. This …
modified pyrrole subunits interconnected at their α carbon atoms via methine bridges. This …