Adsorchromism: Molecular nanoarchitectonics at 2D nanosheets—Old chemistry for advanced chromism

M Eguchi, AS Nugraha, AE Rowan, J Shapter… - Advanced …, 2021 - Wiley Online Library
Chromism induced by changes in the electronic states of dye molecules due to surface
adsorption is termed “adsorchromism” in this article. These changes of molecular electronic …

Designed nanostructures of clay for controlled adsorption of organic compounds

T Okada, Y Seki, M Ogawa - Journal of Nanoscience and …, 2014 - ingentaconnect.com
The utilization of smectite clay, swelling layered silicate, as scaffolds for designing functional
nanostructures was overviewed. Surface modification of smectites with organoammonium …

Size-matching effect on inorganic nanosheets: control of distance, alignment, and orientation of molecular adsorption as a bottom-up methodology for nanomaterials

S Takagi, T Shimada, Y Ishida, T Fujimura, D Masui… - Langmuir, 2013 - ACS Publications
We have been investigating complexes composed of nanolayered materials with anionic
charges such as clay nanosheets and dye molecules such as cationic porphyrins. It was …

“Surface-fixation induced emission” of porphyrazine dye by a complexation with inorganic nanosheets

Y Ishida, T Shimada, S Takagi - The Journal of Physical Chemistry …, 2014 - ACS Publications
This paper proposes a unique phenomenon of the strong enhancement in the fluorescence
quantum yield (φf) and the excited lifetime (τ) of tetra-cationic porphyrazine dye (Pz) upon a …

Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping

K Saito, M Morita, T Okada, M Ogawa - Chemical Society Reviews, 2024 - pubs.rsc.org
Partial replacement of one structural element in a solid with another of a similar size was
conducted to impart functionality to the solids and modify their properties. This phenomenon …

Manipulation of precise molecular arrangements and their photochemical properties on inorganic surfaces via multiple electrostatic interactions

Y Ishida - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Multiple (or multivalent) interaction is the key in many biological systems. One of the most
important (photo-) chemical reactions, photosynthesis, is driven by regularly aligned …

Photophysical properties and adsorption behaviors of novel tri-cationic boron (III) subporphyrin on anionic clay surface

T Tsukamoto, T Shimada, S Takagi - ACS Applied Materials & …, 2016 - ACS Publications
Two types of+ 3-charged subporphyrin derivatives with m-and p-methylpyridinium as the
meso-aryl substituents were designed and synthesized. Their photophysical properties with …

Efficient singlet–singlet energy transfer in a novel host–guest assembly composed of an organic cavitand, aromatic molecules, and a clay nanosheet

Y Ishida, R Kulasekharan, T Shimada, S Takagi… - Langmuir, 2013 - ACS Publications
A supramolecular host–guest assembly composed of a cationic organic cavitand (host),
neutral aromatic molecules (guests), and an anionic clay nanosheet has been prepared and …

Effects of the surface charge density of clay minerals on surface-fixation induced emission of acridinium derivatives

Y Yoshida, T Shimada, T Ishida, S Takagi - ACS omega, 2021 - ACS Publications
Surface-fixation induced emission is a fluorescence enhancement phenomenon, which is
expressed when dye molecules satisfy a specific adsorption condition on the anionic clay …

The Unique Structure–Activity Relationship of Porphyrins and Clay Mineral Systems in Modern Applications: A Comprehensive Review

JH Hassen, J Silver - Chemical and Biochemical Engineering Quarterly, 2024 - hrcak.srce.hr
Sažetak Porphyrins are a group of organic heterocyclic macromolecules, composed of four
modified pyrrole subunits interconnected at their α carbon atoms via methine bridges. This …