Heterometallic 3d–4f Complexes as Single‐Molecule Magnets
Heterometallic 3d‐4f complexes are being investigated, for some time, as being useful in
molecular magnetism, particularly as single‐molecule magnets (SMMs). This interest is …
molecular magnetism, particularly as single‐molecule magnets (SMMs). This interest is …
Air-stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K
Z Zhu, C Zhao, T Feng, X Liu, X Ying, XL Li… - Journal of the …, 2021 - ACS Publications
Design and synthesis of air-stable and easily tailored high-performance single-molecule
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …
Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets
AB Canaj, S Dey, ER Martí, C Wilson… - Angewandte Chemie …, 2019 - Wiley Online Library
Following a novel synthetic strategy where the strong uniaxial ligand field generated by the
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …
Air‐Stable Hexagonal Bipyramidal Dysprosium(III) Single‐Ion Magnets with Nearly Perfect D6h Local Symmetry
ZH Li, YQ Zhai, WP Chen, YS Ding… - Chemistry–A European …, 2019 - Wiley Online Library
Eight‐coordinated DyIII centres with D6h symmetry are expected to act as high‐performance
single‐molecule magnets (SMMs) due to the simultaneous fulfilment of magnetic axiality and …
single‐molecule magnets (SMMs) due to the simultaneous fulfilment of magnetic axiality and …
Pentagonal-bipyramidal 4d and 5d complexes with unquenched orbital angular momentum as a unique platform for advanced single-molecule magnets: Current state …
VS Mironov, TA Bazhenova, YV Manakin… - Dalton …, 2023 - pubs.rsc.org
This article overviews the current state and prospects of the concept of advanced single-
molecule magnets (SMMs) based on low-spin (S= 1/2) pentagonal-bipyramidal (PBP) 4d3 …
molecule magnets (SMMs) based on low-spin (S= 1/2) pentagonal-bipyramidal (PBP) 4d3 …
Engineering macrocyclic high performance pentagonal bipyramidal Dy (III) single-ion magnets
AB Canaj, S Dey, C Wilson, O Céspedes… - Chemical …, 2020 - pubs.rsc.org
We generate a new air-stable pseudo-D5h Dy (III) Single-Molecule Magnet (Ueff= 1108 K,
TB= 14 K) by combining a weak equatorial ligand field from a macrocyclic LN5 ligand with a …
TB= 14 K) by combining a weak equatorial ligand field from a macrocyclic LN5 ligand with a …
A conjugated Schiff-base macrocycle weakens the transverse crystal field of air-stable dysprosium single-molecule magnets
S Liu, Y Gil, C Zhao, J Wu, Z Zhu, XL Li… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Self-condensation of bifunctional 8-aminoquinoline-2-carbaldehyde templated by
dysprosium (III) ions followed by the replacement of axial ligands with triphenylsilanol in the …
dysprosium (III) ions followed by the replacement of axial ligands with triphenylsilanol in the …
Air-stable chiral mono-and dinuclear dysprosium single-molecule magnets: steric hindrance of hexaazamacrocycles
C Zhao, Z Zhu, XL Li, J Tang - Inorganic Chemistry Frontiers, 2022 - pubs.rsc.org
Mononuclear [Dy (L1R/S)(4-Me-PhO) 2](BPh4)(1R/1S) and dinuclear [Dy2 (L2R/S) 2 (4-Me-
PhO) 2 (OH) 2](BPh4) 2 (2R/2S) chiral dysprosium (III) complexes were synthesized using …
PhO) 2 (OH) 2](BPh4) 2 (2R/2S) chiral dysprosium (III) complexes were synthesized using …
Axial ligand as a critical factor for high-performance pentagonal bipyramidal Dy (III) single-ion magnets
B Zhang, X Guo, P Tan, W Lv, X Bai, Y Zhou… - Inorganic …, 2022 - ACS Publications
The choice of axial ligands is of great importance for the construction of high-performance
Dy-based single-molecule magnets (SMMs). Here, combining axial ligands Ph3SiO–(anion …
Dy-based single-molecule magnets (SMMs). Here, combining axial ligands Ph3SiO–(anion …
Two Series of Tetranuclear Ln(III)-Based Clusters: Structures, Magnetic Behaviors, and Efficient Cycloaddition of CO2 to Oxazolidinones
N Qiao, XY Xin, C Yang, M Fang, CX Zhang… - Crystal Growth & …, 2023 - ACS Publications
Four new and interesting Ln4 clusters formulated as [Ln4 (NO3) 2 (acac) 4 (HL1) 2 (CH3OH)
2]· 2 (CH3CN)](Ln= Gd (1), Dy (2); H4L1= 2-(hydroxymethyl)-2-(((2-hydroxynaphthalen-1-yl) …
2]· 2 (CH3CN)](Ln= Gd (1), Dy (2); H4L1= 2-(hydroxymethyl)-2-(((2-hydroxynaphthalen-1-yl) …