Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …
crucial to their catalytic performance. However, the complicated surface and interface …
Methane oxidation to methanol
NF Dummer, DJ Willock, Q He, MJ Howard… - Chemical …, 2022 - ACS Publications
The direct transformation of methane to methanol remains a significant challenge for
operation at a larger scale. Central to this challenge is the low reactivity of methane at …
operation at a larger scale. Central to this challenge is the low reactivity of methane at …
Ensemble effect for single-atom, small cluster and nanoparticle catalysts
A large family of heterogeneous catalytic reactions require active sites with more than one
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
The concept of active site in heterogeneous catalysis
C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …
Stabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane
Copper is the only metal catalyst that can perform the electrocatalytic CO2 reduction reaction
(CRR) to produce hydrocarbons and oxygenates. Its surface oxidation state determines the …
(CRR) to produce hydrocarbons and oxygenates. Its surface oxidation state determines the …
Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Chemical looping-based energy transformation via lattice oxygen modulated selective oxidation
Modulating anionic oxygen in metal oxides offers exceptional opportunities for energy
material synthesis via redox looping; however, several challenges such as overoxidation …
material synthesis via redox looping; however, several challenges such as overoxidation …
Oxo dicopper anchored on carbon nitride for selective oxidation of methane
Selective conversion of methane (CH4) into value-added chemicals represents a grand
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …
Surface coordination chemistry of atomically dispersed metal catalysts
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
Direct conversion of methane with O2 at room temperature over edge-rich MoS2
Conversion of methane to value-added chemicals at low temperature by directly using
inexpensive O2 as oxidant offers an ideal route for methane utilization but remains a great …
inexpensive O2 as oxidant offers an ideal route for methane utilization but remains a great …